Chapter 10: Problem 63
One of the following ions has a trigonal-planar shape: $\mathrm{SO}_{3}^{2-} ; \mathrm{PO}_{4}^{3-} ; \mathrm{PF}_{6}^{-} ; \mathrm{CO}_{3}^{2-} .$ Which ion is it? Explain.
Chapter 10: Problem 63
One of the following ions has a trigonal-planar shape: $\mathrm{SO}_{3}^{2-} ; \mathrm{PO}_{4}^{3-} ; \mathrm{PF}_{6}^{-} ; \mathrm{CO}_{3}^{2-} .$ Which ion is it? Explain.
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Get started for freeThe following polyatomic anions involve covalent bonds between O atoms and the central nonmetal atom. Propose an acceptable Lewis structure for each. (a) \(\mathrm{SO}_{3}^{2-} ;\) (b) \(\mathrm{NO}_{2}^{-} ;\) (c) \(\mathrm{CO}_{3}^{2-} ;\) (d) \(\mathrm{HO}_{2}^{-}\).
Suggest reasons why the following do not exist as stable molecules: (a) \(\mathrm{H}_{3} ;\) (b) \(\mathrm{HHe} ;\) (c) \(\mathrm{He}_{2}\); (d) \(\mathrm{H}_{3} \mathrm{O}\).
Briefly describe each of the following ideas: (a) formal charge; (b) resonance; (c) expanded valence shell; (d) bond energy.
Sodium azide, \(\mathrm{NaN}_{3}\), is the nitrogen gas-forming substance used in automobile air-bag systems. It is an ionic compound containing the azide ion, \(\mathrm{N}_{3}^{-}\). In this ion, the two nitrogen-to-nitrogen bond lengths are \(116 \mathrm{pm} .\) Describe the resonance hybrid Lewis structure of this ion.
Use the \(\mathrm{NH}_{3}\) molecule as an example to explain the difference between molecular geometry and electron-group geometry.
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