Chapter 11: Problem 107
Construct a concept map that connects the ideas of molecular orbital theory.
Chapter 11: Problem 107
Construct a concept map that connects the ideas of molecular orbital theory.
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Get started for freeWrite Lewis structures for the following molecules, and then label each \(\sigma\) and \(\pi\) bond. (a) \(\mathrm{HCN} ;\) (b) \(\mathrm{C}_{2} \mathrm{N}_{2}\) (c) \(\mathrm{CH}_{3} \mathrm{CHCHCCl}_{3} ;\) (d) HONO.
The anion \(I_{4}^{2-}\) is linear, and the anion \(I_{5}^{-}\) is V-shaped, with a \(95^{\circ}\) angle between the two arms of the V. For the central atoms in these ions, propose hybridization schemes that are consistent with these observations.
Construct a molecular orbital diagram for \(\mathrm{HF}\), and label the molecular orbitals as bonding, antibonding, or nonbonding.
The paramagnetism of gaseous \(\mathrm{B}_{2}\) has been established. Explain how this observation confirms that the \(\pi_{2 p}\) orbitals are at a lower energy than the \(\sigma_{2 p}\) orbital for \(\mathrm{B}_{2}\)
The molecule formamide, \(\mathrm{HCONH}_{2}\), has the approximate bond angles \(\mathrm{H}-\mathrm{C}-\mathrm{O}, 123^{\circ} ; \mathrm{H}-\mathrm{C}-\mathrm{N}, 113^{\circ}\) \(\mathrm{N}-\mathrm{C}-\mathrm{O}, 124^{\circ} ; \mathrm{C}-\mathrm{N}-\mathrm{H}, 119^{\circ} ; \mathrm{H}-\mathrm{N}-\mathrm{H}, 119^{\circ}\) The \(\mathrm{C}-\mathrm{N}\) bond length is \(138 \mathrm{pm}\). Two Lewis structures can be written for this molecule, with the true structure being a resonance hybrid of the two. Propose a hybridization and bonding scheme for each structure.
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