Is it possible to obtain a sample of ice from liquid water without ever putting the water in a freezer or other enclosure at a temperature below \(0^{\circ} \mathrm{C} ?\) If \(\mathrm{so}\) how might this be done?

Short Answer

Expert verified
Yes, it is theoretically possible to freeze water without it being at a temperature below \(0^{\circ} \mathrm{C}\) . To do this, the pressure on the water would need to be decreased significantly. However, in practical terms, this would be extremely difficult without specialised equipment.

Step by step solution

01

Understanding the Problem

The problem is asking if it's possible to freeze water without having its temperature drop below \(0^{\circ} \mathrm{C}\). By everyday experience, we know that water freezes at \(0^{\circ} \mathrm{C}\), however, this problem is asking to think outside of everyday experience and consider scientific principles.
02

Understanding Phase Changes

Phase changes are typically presented as a function of temperature; however, they also depend on pressure. Mentioning both elements, we can understand that changing either attribute can trigger a phase change. Usually, a decrease in pressure lets a substance boil at lower temperatures. This also works in reverse with freezing - that a decrease in pressure can cause water to freeze at a higher temperature.
03

Final Solution

Applying these principles of phase changes, it's theoretically possible to freeze water without it being at a temperature below 0°C. To do this we would need to decrease the pressure on the water significantly. However, in practice, this would be extremely difficult to do without specialised equipment and is far beyond the range of pressures that we typically encounter in our daily life. In most situations, the simplest and most practical way to freeze water is to lower its temperature below \(0^{\circ} \mathrm{C}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Freezing Point Depression
Freezing point depression is a phenomenon that occurs when a substance's freezing point is lowered by the addition of another substance, such as a solute in a solvent. Consider salt sprinkled on icy roads: the salt dissolves in the ice (solid state water), creating a salt-water solution that has a lower freezing point than pure water. This means that the ice will melt at temperatures below the normal freezing point of water, which is 0°C.
This concept is not only useful for practical applications like de-icing but it is also critical in many industrial processes and in the study of antifreeze in biological organisms. In a laboratory, freezing point depression can be used to determine molecular weights of solutes in a solution. By measuring the degree to which the freezing point of a solvent is lowered by the addition of a solute, you can calculate the molar mass of the solute.
In our original exercise, the added component could be a solute, but it also hints at the possibilities of freezing water by methods that don't involve temperature alone, such as pressure alterations.
Phase Diagrams
Phase diagrams are charts that show the state of matter at various pressures and temperatures. They tend to feature three regions representative of solids, liquids, and gases, along with lines that indicate the conditions under which equilibrium phase changes occur.
Take water, for example. On a phase diagram for water, you would see lines that indicate the temperatures and pressures at which water transitions between being a solid (ice), liquid (water), and gas (steam). It is notable that these diagrams also display a point known as the 'triple point,' where all three phases can coexist in equilibrium. Moreover, there's a 'critical point' where the distinction between liquid and gas phases ceases to exist.
Learning to read phase diagrams not only helps in visualizing the conditions for phase changes but also provides insight into phenomena such as freezing water under conditions that don't involve low temperatures, which ties directly into our exercise problem and solution.
States of Matter
Matter typically exists in one of three states: solid, liquid, and gas. These states are strongly dependent on temperature and pressure. At 1 atmosphere of pressure, we are familiar with water freezing at 0°C and boiling at 100°C, but these temperature points change at different pressures.
  • Solid: Particles are closely packed in a regular pattern. Solids have a definite shape and volume.
  • Liquid: Particles are close together with some ability to move around. Liquids have a definite volume, but not a definite shape.
  • Gas: Particles are well separated with lots of room to move. Gases have neither definite volume nor shape.
When substances change from one state to another—like freezing or boiling—we call these transitions 'phase changes.' These are often shown as straight lines on a phase diagram, representing the equilibrium between phases under different conditions of temperature and pressure. The 'step-by-step solution' to our exercise utilizes these principles to imagine freezing water without a low temperature by altering pressure.

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Most popular questions from this chapter

In ionic compounds with certain metals, hydrogen exists as the hydride ion, \(\mathrm{H}^{-}\). Determine the electron affinity of hydrogen; that is, \(\Delta H\) for the process \(\mathrm{H}(\mathrm{g})+e^{-} \rightarrow \mathrm{H}^{-}(\mathrm{g}) .\) To do so, use data from Section \(12-7 ;\) the bond energy of \(\mathrm{H}_{2}(\mathrm{g})\) from table 10.3 \(-812 \mathrm{kJmol}^{-1} \mathrm{NaH}\) for the lattice energy of \(\mathrm{NaH}(\mathrm{s})\) and \(-57 \mathrm{kJmol}^{-1}\) NaH for the enthalpy of formation of \(\mathrm{NaH}(\mathrm{s})\)

In which of the following compounds do you think that intramolecular hydrogen bonding is an important factor: $(\mathrm{a}) \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3} ;(\mathrm{b}) \mathrm{HOOCCH}_{2} \mathrm{CH}_{2}$ $\mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{COOH} ;(\mathrm{c}) \mathrm{CH}_{3} \mathrm{COOH} ;$ (d) ortho-phthalic acid? Explain.

Trace the phase changes that occur as a sample of \(\mathrm{H}_{2} \mathrm{O}(\mathrm{g}),\) originally at \(1.00 \mathrm{mmHg}\) and \(-0.10^{\circ} \mathrm{C},\) is compressed at constant temperature until the pressure reaches 100 atm.

A crystalline solid contains three types of ions, \(\mathrm{Na}^{+}, \mathrm{O}^{2-},\) and \(\mathrm{Cl}^{-}\). The solid is made up of cubic unit cells that have \(\mathrm{O}^{2-}\) ions at each corner, \(\mathrm{Na}^{+}\) ions at the center of each face, and \(\mathrm{Cl}^{-}\) ions at the center of the cells. What is the chemical formula of the compound? What are the coordination numbers for the \(\mathrm{O}^{2-}\) and \(\mathrm{Cl}^{-}\) ions? If the length of one edge of the unit cell is \(a,\) what is the shortest distance from the center of a \(\mathrm{Na}^{+}\) ion to the center of an \(\mathrm{O}^{2-}\) ion? Similarly, what is the shortest distance from the center of a \(\mathrm{Cl}^{-}\) ion to the center of an \(\mathrm{O}^{2-}\) ion?

The normal melting point of copper is \(1357 \mathrm{K}\), and \(\Delta \mathrm{H}_{\text {fus }}\) of \(\mathrm{Cu}\) is \(13.05 \mathrm{kJ} \mathrm{mol}^{-1}\). (a) How much heat, in kilojoules, is evolved when a \(3.78 \mathrm{kg}\) sample of molten Cu freezes? (b) How much heat, in kilojoules, must be absorbed at 1357 K to melt a bar of copper that is \(75 \mathrm{cm} \times\) \(15 \mathrm{cm} \times 12 \mathrm{cm} ?\) (Assume \(d=8.92 \mathrm{g} / \mathrm{cm}^{3}\) for \(\mathrm{Cu}\).)

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