Chapter 12: Problem 8
What is the maximum number of hydrogen bonds that can form between two acetic acid molecules?
Chapter 12: Problem 8
What is the maximum number of hydrogen bonds that can form between two acetic acid molecules?
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Get started for freeConstruct a concept map using the ideas of packing of spheres and the structure of metal and ionic crystals.
Would you expect an ionic solid or a network covalent solid to have the higher melting point?
Determine the lattice energy of \(\mathrm{KF}(\mathrm{s})\) from the following data: \(\Delta \mathrm{H}_{\mathrm{f}}[\mathrm{KF}(\mathrm{s})]=-567.3 \mathrm{kJ} \mathrm{mol}^{-1} ;\) enthalpy of sub- limation of \(\mathrm{K}(\mathrm{s}), 89.24 \mathrm{kJ} \mathrm{mol}^{-1} ;\) enthalpy of dissociation of \(\mathrm{F}_{2}(\mathrm{g}), 159 \mathrm{kJ} \mathrm{mol}^{-1} \mathrm{F}_{2} ; I_{1}\) for \(\mathrm{K}(\mathrm{g}), 418.9 \mathrm{kJmol}^{-1}\) EA for \(\mathrm{F}(\mathrm{g}),-328 \mathrm{kJ} \mathrm{mol}^{-1}\)
The normal melting point of copper is \(1357 \mathrm{K}\), and \(\Delta \mathrm{H}_{\text {fus }}\) of \(\mathrm{Cu}\) is \(13.05 \mathrm{kJ} \mathrm{mol}^{-1}\). (a) How much heat, in kilojoules, is evolved when a \(3.78 \mathrm{kg}\) sample of molten Cu freezes? (b) How much heat, in kilojoules, must be absorbed at 1357 K to melt a bar of copper that is \(75 \mathrm{cm} \times\) \(15 \mathrm{cm} \times 12 \mathrm{cm} ?\) (Assume \(d=8.92 \mathrm{g} / \mathrm{cm}^{3}\) for \(\mathrm{Cu}\).)
If the triple point pressure of a substance is greater than 1 atm, which two of the following conclusions are valid? (a) The solid and liquid states of the substance cannot coexist at equilibrium. (b) The melting point and boiling point of the substance are identical. (c) The liquid state of the substance cannot exist. (d) The liquid state cannot be maintained in a beaker open to air at 1 atm pressure. (e) The melting point of the solid must be greater than \(0^{\circ} \mathrm{C}\) (f) The gaseous state at 1 atm pressure cannot be condensed to the solid at the triple point temperature.
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