Chapter 12: Problem 9
In DNA the nucleic acid bases form hydrogen bonds between them, which are responsible for the formation of the double-stranded helix. Arrange the bases guanine and cytosine to give the maximum number of hydrogen bonds.
Chapter 12: Problem 9
In DNA the nucleic acid bases form hydrogen bonds between them, which are responsible for the formation of the double-stranded helix. Arrange the bases guanine and cytosine to give the maximum number of hydrogen bonds.
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Get started for freeWithout doing calculations, indicate how you would expect the lattice energies of \(\mathrm{LiCl}(\mathrm{s}), \mathrm{KCl}(\mathrm{s}), \mathrm{RbCl}(\mathrm{s}),\) and \(\mathrm{CsCl}(\mathrm{s})\) to compare with the value of \(-787 \mathrm{kJmol}^{-1}\) determined for \(\mathrm{NaCl}(\mathrm{s})\) on page \(543 .\) [ Hint: Assume that the enthalpies of sublimation of the alkali metals are comparable in value. What atomic properties from Chapter 9 should you compare?
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A vapor volume of 1.17 L forms when a sample of liquid acetonitrile, \(\mathrm{CH}_{3} \mathrm{CN},\) absorbs \(1.00 \mathrm{kJ}\) of heat at its normal boiling point \(\left(81.6^{\circ} \mathrm{C} \text { and } 1 \mathrm{atm}\right) .\) What is \(\Delta H_{\text {vap }}\) in kilojoules per mole of \(\mathrm{CH}_{3} \mathrm{CN} ?\)
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