Without doing detailed calculations, determine which of the following samples has the greatest number of atoms: (a) a cube of iron with a length of \(10.0 \mathrm{cm}\) \(\left(d=7.86 \mathrm{g} / \mathrm{cm}^{3}\right)\) (b) \(1.00 \mathrm{kg}\) of hydrogen contained in a \(10,000 \mathrm{L}\) balloon (c) a mound of sulfur weighing \(20.0 \mathrm{kg}\) (d) a 76 lb sample of liquid mercury \((d=13.5 \mathrm{g} / \mathrm{mL})\)

Short Answer

Expert verified
The sample of hydrogen has the greatest number of atoms.

Step by step solution

01

Cube of Iron

Calculate the mass of the cube of iron using its volume and density. Given that the length, height, and width of the cube are each equal to \(10.0 cm\), its volume is \(1000 cm^3\). Then, given that density is defined as mass divided by volume, the iron's mass is its volume times its density \(d=7.86 g/cm^3\). Therefore, the iron cube's mass is \(7860 g\). Using the molar mass of iron (\(55.85 g/mol\)), we can then calculate the number of moles in the cube, and then the number of atoms using Avogadro's constant (\(6.022 \times 10^{23} atoms/mol\)).
02

Hydrogen Balloon

The mass of hydrogen is given directly as \(1.00 kg\), which is equivalent to \(1000 g\). We can then use this mass and the molar mass of hydrogen (\(1.01 g/mol\)) to calculate the number of moles and then the number of atoms, as in Step 1.
03

Sulfur Mound

The mass of the mound of sulfur is given directly as \(20.0 kg\), which is equivalent to \(20000 g\). We can then use this mass and the molar mass of sulfur (\(32.07 g/mol\)) to calculate the number of moles, and then the number of atoms as in the previous steps.
04

Mercury Sample

First, convert the weight of the mercury sample from pounds to grams (\(1 lb = 454 g\)), obtaining roughly \(34504 g\). Then, using the molar mass of mercury (\(200.59 g/mol\)), calculate the number of moles, and then the number of atoms as in previous steps.
05

Comparison

Now compare the four calculated numbers of atoms. The sample with the greatest number has the greatest quantity of atoms.

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