For the reduction half-reaction \(\mathrm{Hg}_{2}^{2+}(\mathrm{aq})+2 \mathrm{e}^{-}\) \(\longrightarrow 2 \mathrm{Hg}(1), E^{\circ}=0.797 \mathrm{V} .\) Will \(\mathrm{Hg}(\mathrm{l})\) react with and dissolve in HCl(aq)? in HNO3(aq)? Explain.

At the heart of chemistry lies the concept of chemical reactions, which are processes that involve the transformation of one set of chemical substances into another. These processes can be categorized into various types, such as synthesis, decomposition, single replacement, and double replacement reactions.

Understanding chemical reactions is crucial when predicting the behavior of substances under different conditions. For instance, whether mercury (I) will react and dissolve in hydrochloric acid (HCl) or nitric acid (HNO3) can be inferred from knowing the type of chemical reaction that could take place. In the case of mercury's interactions with these acids, a single replacement reaction might occur, where mercury would potentially replace another element in a compound.

Electrochemical reactions comprise two half-reactions: oxidation and reduction. The reduction half-reaction involves the gain of electrons. In order to understand whether a metal will react with an acid, chemists look at the standard reduction potentials.

For instance, the reduction half-reaction for mercury (I) ions, \(\mathrm{Hg}_{2}^{2+} + 2 \mathrm{e}^{-} \rightarrow 2 \mathrm{Hg}(\ell)\), indicates that mercury ions gain electrons to become liquid mercury. The standard reduction potential associated with this half-reaction provides insight into its likelihood to proceed when compared to other potential reduction reactions, such as those involving HCl or HNO3. The potential needs to be compared to those of other potential reactants to determine which substance gets reduced preferentially.

Electrochemistry is the branch of chemistry that deals with the relationship between electricity and chemical change. At the core of electrochemistry are the concepts of oxidation and reduction, where electrons transfer between reactants.

In the context of electrochemistry, the standard reduction potential is a measure of the tendency of a chemical species to be reduced, and it is quantified under standard conditions. A higher standard reduction potential indicates a stronger tendency to gain electrons and be reduced. Thus, by comparing the standard reduction potentials of the mercury (I) reduction half-reaction with those involving HCl and HNO3, we can predict the sequence of reactivity and determine whether mercury (I) will dissolve in those acids.