Chapter 22: Problem 10
Write a chemical equation for the hydrolysis in alkaline solution of \(\mathrm{XeF}_{6}\) that yields \(\mathrm{XeO}_{6}^{4-}, \mathrm{Xe}, \mathrm{O}_{2}, \mathrm{F}^{-}\) and \(\mathrm{H}_{2} \mathrm{O}\) as products.
Chapter 22: Problem 10
Write a chemical equation for the hydrolysis in alkaline solution of \(\mathrm{XeF}_{6}\) that yields \(\mathrm{XeO}_{6}^{4-}, \mathrm{Xe}, \mathrm{O}_{2}, \mathrm{F}^{-}\) and \(\mathrm{H}_{2} \mathrm{O}\) as products.
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Get started for freeIn your own words, define the following terms: (a) polyhalide ion; (b) polyphosphate; (c) interhalogen; (d) disproportionation.
Polonium is the only element known to crystallize in the simple cubic form. In this structure, the interatomic distance between a Po atom and each of its six nearest neighbors is \(335 \mathrm{pm}\). Use this description of the crystal structure to estimate the density of polonium.
Although relatively rare, all of the following compounds exist. Based on what you know about related compounds (for example, from the periodic table), propose a plausible name or formula for each compound: (a) silver(I) astatide; (b) \(\mathrm{Na}_{4} \mathrm{XeO}_{6} ;\) (c) magnesium polonide; (d) \(\mathrm{H}_{2} \mathrm{TeO}_{3} ;\) (e) potassium thioselenate; (f) \(\mathrm{KAtO}_{4}\).
When heated, each of the following substances decomposes to the products indicated. Write balanced equations for these reactions. (a) \(\mathrm{NH}_{4} \mathrm{NO}_{3}(\mathrm{s})\) to \(\mathrm{N}_{2}(\mathrm{g}), \mathrm{O}_{2}(\mathrm{g}),\) and \(\mathrm{H}_{2} \mathrm{O}(\mathrm{g})\) (b) \(\mathrm{NaNO}_{3}(\mathrm{s})\) to sodium nitrite and oxygen gas (c) \(\mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}(\mathrm{s})\) to lead(II) oxide, nitrogen dioxide, and oxygen.
Joseph Priestley, a British chemist, was credited with the discovering oxygen in \(1774 .\) In his experiments, he generated oxygen gas by heating \(\mathrm{HgO}(\mathrm{s}) .\) The other product of the decomposition reaction is \(\mathrm{Hg}(1) .\) What volume of wet \(\mathrm{O}_{2}(\mathrm{g})\) is obtained from the decomposition of \(1.0 \mathrm{g} \mathrm{HgO}(\mathrm{s}),\) if the gas is collected over water at \(25^{\circ} \mathrm{C}\) and a barometric pressure of \(756 \mathrm{mmHg} ?\) The vapor pressure of water is \(23.76 \mathrm{mmHg}\) at \(25^{\circ} \mathrm{C}\).
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