Chapter 22: Problem 4
The oxides of the selenium(IV) and tellurium(IV) are \(\mathrm{SeO}_{2}\) and \(\mathrm{TeO}_{2} .\) One of these oxides is amphoteric and one is acidic. Which is which?
Chapter 22: Problem 4
The oxides of the selenium(IV) and tellurium(IV) are \(\mathrm{SeO}_{2}\) and \(\mathrm{TeO}_{2} .\) One of these oxides is amphoteric and one is acidic. Which is which?
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Get started for free\(\mathrm{O}_{3}(\mathrm{g})\) is a powerful oxidizing agent. Write equations to represent oxidation of \((a) I^{-}\) to \(I_{2}\) in acidic solution; (b) sulfur in the presence of moisture to sulfuric acid; (c) \(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{4-}\) to \(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-}\) in basic solution. In each case \(\mathrm{O}_{3}(\mathrm{g})\) is reduced to \(\mathrm{O}_{2}(\mathrm{g})\).
Without doing detailed calculations, explain in which of the following materials you would expect to find the greatest mass percent of hydrogen: seawater, the atmosphere, natural gas \(\left(\mathrm{CH}_{4}\right),\) ammonia.
Show by calculation whether the reaction $2 \mathrm{HOCl}(\mathrm{aq}) \longrightarrow \mathrm{HClO}_{2}(\mathrm{aq})+\mathrm{H}^{+}(\mathrm{aq})+\mathrm{Cl}^{-}(\mathrm{aq})$ will go essentially to completion as written for standardstate conditions.
Give an appropriate name to each of the following compounds: (a) \(\mathrm{ZnS} ;\) (b) \(\mathrm{KHSO}_{3} ;\) (c) \(\mathrm{K}_{2} \mathrm{S}_{2} \mathrm{O}_{3} ;\) (d) \(\mathrm{SF}_{4}\).
The trichloride ion, \(\mathrm{Cl}_{3}^{-1}\), is not very stable in aqueous solution. The equilibrium constant for the following dissociation reaction is 5.5 at \(25^{\circ} \mathrm{C}\) : $$\mathrm{Cl}_{3}^{-}(\mathrm{aq}) \rightleftharpoons \mathrm{Cl}^{-}(\mathrm{aq})+\mathrm{Cl}_{2}(\mathrm{aq})$$ (a) Draw a Lewis structure for the \(\mathrm{Cl}_{3}^{-}\) ion and predict the geometry. (b) Calculate the equilibrium concentration of \(\mathrm{Cl}_{3}^{-}\) if 0.0010 moles each of \(\mathrm{KCl}\) and \(\mathrm{Cl}_{2}\) are dissolved in water at \(25^{\circ} \mathrm{C}\) to make \(1.0 \mathrm{L}\) of solution.
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