Chapter 23: Problem 76
In your own words, define the following terms: (a) domain; (b) flotation; (c) leaching; (d) amalgam.
Chapter 23: Problem 76
In your own words, define the following terms: (a) domain; (b) flotation; (c) leaching; (d) amalgam.
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Get started for freeWhat products are obtained when \(\mathrm{Mg}^{2+}(\mathrm{aq})\) and \(\mathrm{Cr}^{3+}(\mathrm{aq})\) are each treated with a limited amount of NaOH(aq)? With an excess of \(\mathrm{NaOH}(\) aq)? Why are the results different in these two cases?
Explain why gold dissolves in aqua regia but not in \(\mathrm{HNO}_{3}(\mathrm{aq})\).
You are given these three reducing agents: \(\mathrm{Zn}(\mathrm{s})\) \(\mathrm{Sn}^{2+}(\mathrm{aq}),\) and \(\mathrm{I}^{-}(\mathrm{aq}) .\) Use data from Appendix \(\mathrm{D}\) to determine which of them can, under standard-state conditions in acidic solution, reduce (a) \(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}(\mathrm{aq})\) to \(\mathrm{Cr}^{3+}(\mathrm{aq})\) (b) \(\mathrm{Cr}^{3+}(\text { aq })\) to \(\mathrm{Cr}^{2+}(\mathrm{aq})\) (c) \(\mathrm{SO}_{4}^{2-}(\text { aq })\) to \(\mathrm{SO}_{2}(\mathrm{g})\)
When a soluble lead compound is added to a solution containing primarily orange dichromate ion, yellow lead chromate precipitates. Describe the equilibria involved.
A 0.589 g sample of pyrolusite ore (impure \(\mathrm{MnO}_{2}\) ) is treated with \(1.651 \mathrm{g}\) of oxalic acid \(\left(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4} \cdot 2 \mathrm{H}_{2} \mathrm{O}\right)\) in an acidic medium (reaction 1). Following this, the excess oxalic acid is titrated with \(30.06 \mathrm{mL}\) of \(0.1000 \mathrm{M}\) \(\mathrm{KMnO}_{4}\) (reaction 2). What is the mass percent of \(\mathrm{MnO}_{2}\) in the pyrolusite? The following equations are neither complete nor balanced. (1) \(\quad \mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(\mathrm{aq})+\mathrm{MnO}_{2}(\mathrm{s}) \longrightarrow \mathrm{Mn}^{2+}(\mathrm{aq})+\mathrm{CO}_{2}(\mathrm{g})\) (2) \(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(\mathrm{aq})+\mathrm{MnO}_{4}^{-}(\mathrm{aq}) \longrightarrow \mathrm{Mn}^{2+}(\mathrm{aq})+\mathrm{CO}_{2}(\mathrm{g})\)
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