Chapter 23: Problem 79
Describe the chemical composition of the material called (a) pig iron; (b) ferromanganese alloy; (c) chromite ore; (d) brass; (e) aqua regia; (f) blister copper; (g) stainless steel.
Chapter 23: Problem 79
Describe the chemical composition of the material called (a) pig iron; (b) ferromanganese alloy; (c) chromite ore; (d) brass; (e) aqua regia; (f) blister copper; (g) stainless steel.
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Get started for freeA solution is believed to contain one or more of the following ions: \(\mathrm{Cr}^{3+}, \mathrm{Zn}^{2+}, \mathrm{Fe}^{3+}, \mathrm{Ni}^{2+} .\) When the solution is treated with excess \(\mathrm{NaOH}(\mathrm{aq}),\) a precipitate forms. The solution in contact with the precipitate is colorless. The precipitate is dissolved in \(\mathrm{HCl}(\mathrm{aq}),\) and the resulting solution is treated with \(\mathrm{NH}_{3}(\text { aq })\). No precipitation occurs. Based solely on these observations, what conclusions can you draw about the ions present in the original solution? That is, which ion(s) are likely present, which are most likely not present, and about which can we not be certain? [Hint: Refer to Appendix D for solubility product and complex-ion formation data.
Attempts to make \(\mathrm{CuI}_{2}\) by the reaction of \(\mathrm{Cu}^{2+}(\mathrm{aq})\) and \(\mathrm{I}^{-}(\text {aq })\) produce \(\mathrm{CuI}(\mathrm{s})\) and \(\mathrm{I}_{3}^{-}(\mathrm{aq})\) instead. Without performing detailed calculations, show why this reaction should occur. $$2 \mathrm{Cu}^{2+}(\mathrm{aq})+5 \mathrm{I}^{-}(\mathrm{aq}) \longrightarrow 2 \mathrm{CuI}(\mathrm{s})+\mathrm{I}_{3}^{-}(\mathrm{aq})$$
Suggest a series of reactions, using common chemicals, by which each of the following syntheses can be performed. (a) \(\mathrm{Cu}(\mathrm{OH})_{2}(\mathrm{s})\) from \(\mathrm{CuO}(\mathrm{s})\) (b) \(\operatorname{Cr} \mathrm{Cl}_{3}\left(\text { aq) } \text { from }\left(\mathrm{NH}_{4}\right)_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}(\mathrm{s})\right.\)
Covalent bonding is involved in many transition metal compounds. Draw Lewis structures, showing any nonzero formal charges, for the following molecules or ions: (a) \(\mathrm{Hg}_{2}^{2+} ;\) (b) \(\mathrm{Mn}_{2} \mathrm{O}_{7} ;\) (c) \(\mathrm{OsO}_{4}\). [Hint: In (b), there is one \(\mathrm{Mn}-\mathrm{O}-\text { Mn linkage in the molecule. }\rfloor\)
Nitinol is a nickel-titanium alloy known as memory metal. The name nitinol is derived from the symbols for nickel (Ni), titanium (Ti), and the acronym for the Naval Ordinance Laboratory (NOL), where it was discovered. If an object made out of nitinol is heated to about \(500^{\circ} \mathrm{C}\) for about an hour and then allowed to cool, the original shape of the object is "remembered," even if the object is deformed into a different shape. The original shape can be restored by heating the metal. Because of this property, nitinol has found many uses, especially in medicine and orthodontics (for braces). Nitinol exists in a number of different solid phases. In the so- called austerite phase, the metal is relatively soft and elastic. The crystal structure for the austerite phase can be described as a simple cubic lattice of Ti atoms with Ni atoms occupying cubic holes in the lattice of Ti atoms. What is the empirical formula of nitinol and what is the percent by mass of titanium in the alloy?
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