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Chapter 26: Problem 30

Give the isomers with molecular formula \(\mathrm{C}_{5} \mathrm{H}_{10} \mathrm{O}_{2}\) that contain more than one functional group.

Short Answer

Expert verified
The isomers of \( C_{5} H_{10} O_{2} \) that contain more than one functional group are \( CH_{2}COOH-CH_{2}-CHO \), \( CH_{2}COOH-CH-CH_{2}-CHO \), and \( CH_{2}COO-CH_{2}-CHO \).

Step by step solution

01

Identify the Functional Groups

Functional groups that comprise the molecular formula \( C_{5} H_{10} O_{2} \) include: the Carboxyl group (-COOH), the Aldehyde group (-CHO), and the Ester group (-COOR). It's crucial to remember that a molecule can have more than one functional group.
02

Construct Isomers

Now, start by creating isomers with more than one functional group: \n\n1. The first isomer contains one Carboxyl group and one Aldehyde group. This corresponds to a 4-carbon chain with a Carboxyl group at one end and an Aldehyde group at the other end: \( CH_{2}COOH-CH_{2}-CHO \).\n\n2. The second isomer contains one Carboxyl group and one Aldehyde group. This corresponds to a 5-carbon chain with a Carboxyl group at one end and an Aldehyde group in the middle of the chain: \( CH_{2}COOH-CH-CH_{2}-CHO \). \n\n3. The third isomer contains one Ester group and one Aldehyde group. This represents a 5-carbon chain with an Ester group in the middle and an Aldehyde group at one end: \( CH_{2}COO-CH_{2}-CHO \).
03

Check for More Isomers

Rotate and rearrange atoms and bonds to ensure all possible isomers are found.

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Most popular questions from this chapter

Identify the functional group in each compound (i.e., alcohol, amine, etc.). (a) \(\mathrm{CH}_{3} \mathrm{CHBrCH}_{2} \mathrm{CH}_{3}\) (b) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CH}_{2} \mathrm{CHO}\) (c) \(\mathrm{CH}_{3} \mathrm{COCH}_{2} \mathrm{CH}_{3}\) (d) \(\mathrm{C}_{6} \mathrm{H}_{4}(\mathrm{OH})_{2}\).

Draw and name all derivatives of benzene having the formula (a) \(\mathrm{C}_{8} \mathrm{H}_{10} ;\) (b) \(\mathrm{C}_{9} \mathrm{H}_{12}\).

Identify the functional group in each compound (i.e., alcohol, amine, etc.). (a) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{COOH}\) (b) \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHCH}_{2} \mathrm{OCH}_{3}\) (c) \(\mathrm{CH}_{3} \mathrm{CH}\left(\mathrm{NH}_{2}\right) \mathrm{CH}_{2} \mathrm{CH}_{3}\) (d) \(\mathrm{CH}_{3} \mathrm{COOCH}_{3}\).

The functional groups in each of the following pairs have certain features in common, but what is the essential difference between them? (a) carbonyl and carboxyl (b) aldehyde and ketone (c) acetic acid and acetyl group

Write structural formulas for the following. (a) 2,4 -dimethyl- 1,4 -pentadiene (b) 2,3 -dimethylpentane (c) 1,2,4 -tribromobenzene (d) methylethanoate (e) butanone
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