Chapter 26: Problem 82
Draw and name all derivatives of benzene having the formula (a) \(\mathrm{C}_{8} \mathrm{H}_{10} ;\) (b) \(\mathrm{C}_{9} \mathrm{H}_{12}\).
Chapter 26: Problem 82
Draw and name all derivatives of benzene having the formula (a) \(\mathrm{C}_{8} \mathrm{H}_{10} ;\) (b) \(\mathrm{C}_{9} \mathrm{H}_{12}\).
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Get started for freeDraw the structure for each of the following. (a) \((Z)-1,3,5\) -tribromo- 2 -pentene (b) \((E)-1,2\) -dibromo- 3 -methyl- 2 -hexene (c) (S)-1-bromo-1-chlorobutane (d) \((R)-1,3\) -dibromohexane (e) (S)-1-chloro-2-propanol.
Combustion of a \(0.1908 \mathrm{g}\) sample of a compound gave \(0.2895 \mathrm{g} \mathrm{CO}_{2}\) and \(0.1192 \mathrm{g} \mathrm{H}_{2} \mathrm{O} .\) Combustion of a second sample weighing \(0.1825 \mathrm{g}\) yielded \(40.2 \mathrm{mL}\) of \(\mathrm{N}_{2}(\mathrm{g}),\) collected over \(50 \% \mathrm{KOH}(\mathrm{aq})\) (vapor pressure \(=\) \(9 \mathrm{mmHg}\) ) at \(25^{\circ} \mathrm{C}\) and \(735 \mathrm{mm} \mathrm{Hg}\) barometric pressure. When \(1.082\mathrm{g}\) of compound was dissolved in \(26.00 \mathrm{g}\) benzene \(\left(\mathrm{mp} 5.50^{\circ} \mathrm{C}, K_{\mathrm{f}}=5.12^{\circ} \mathrm{C} m^{-1}\right),\) the solution had a freezing point of \(3.66^{\circ} \mathrm{C}\). What is the molecular formula of this compound?
Write structural formulas for the following. (a) 2,4 -dimethyl- 1,4 -pentadiene (b) 2,3 -dimethylpentane (c) 1,2,4 -tribromobenzene (d) methylethanoate (e) butanone
Consider the following molecular formulas. How many elements of unsaturation are there in each case? (a) \(\mathrm{C}_{4} \mathrm{H}_{11} \mathrm{N} ;\) (b) \(\mathrm{C}_{4} \mathrm{H}_{6} \mathrm{O} ;\) (c) \(\mathrm{C}_{9} \mathrm{H}_{15} \mathrm{ClO}\).
Describe the characteristics of each of the following types of isomers: (a) constitutional; (b) stereoisomer; (c) cis; (d) ortho.
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