Chapter 26: Problem 87
Write structural formulas for all the isomers of \(\mathrm{C}_{4} \mathrm{H}_{7} \mathrm{Cl}\). Indicate any enantiomers or diastereomers that occur.
Chapter 26: Problem 87
Write structural formulas for all the isomers of \(\mathrm{C}_{4} \mathrm{H}_{7} \mathrm{Cl}\). Indicate any enantiomers or diastereomers that occur.
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Get started for freeCombustion of a \(0.1908 \mathrm{g}\) sample of a compound gave \(0.2895 \mathrm{g} \mathrm{CO}_{2}\) and \(0.1192 \mathrm{g} \mathrm{H}_{2} \mathrm{O} .\) Combustion of a second sample weighing \(0.1825 \mathrm{g}\) yielded \(40.2 \mathrm{mL}\) of \(\mathrm{N}_{2}(\mathrm{g}),\) collected over \(50 \% \mathrm{KOH}(\mathrm{aq})\) (vapor pressure \(=\) \(9 \mathrm{mmHg}\) ) at \(25^{\circ} \mathrm{C}\) and \(735 \mathrm{mm} \mathrm{Hg}\) barometric pressure. When \(1.082\mathrm{g}\) of compound was dissolved in \(26.00 \mathrm{g}\) benzene \(\left(\mathrm{mp} 5.50^{\circ} \mathrm{C}, K_{\mathrm{f}}=5.12^{\circ} \mathrm{C} m^{-1}\right),\) the solution had a freezing point of \(3.66^{\circ} \mathrm{C}\). What is the molecular formula of this compound?
Supply a name or structural formula for each of the following. (a) phenylacetylene (b) \(m\) -dichlorobenzene
Draw Lewis structures of the following simple organic molecules: (a) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{COOH} ;\) (b) \(\mathrm{H}_{3} \mathrm{CCN}\) (c) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{NH}_{2}\).
Use the half-reaction method to balance the following redox equations. (a) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Fe}+\mathrm{H}^{+} \longrightarrow\) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NH}_{3}^{+}+\mathrm{Fe}^{3+}+\mathrm{H}_{2} \mathrm{O}\) (b) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CH}_{2} \mathrm{OH}+\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}+\mathrm{H}^{+} \longrightarrow\) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CO}_{2} \mathrm{H}+\mathrm{Cr}^{3+}+\mathrm{H}_{2} \mathrm{O}\) (c) \(\mathrm{CH}_{3} \mathrm{CH}=\mathrm{CH}_{2}+\mathrm{MnO}_{4}^{-}+\mathrm{H}_{2} \mathrm{O} \longrightarrow\) \(\mathrm{CH}_{3} \mathrm{CHOHCH}_{2} \mathrm{OH}+\mathrm{MnO}_{2}+\mathrm{OH}^{-}\).
Consider the following molecular formulas. How many elements of unsaturation are there in each case? (a) \(\mathrm{C}_{4} \mathrm{H}_{11} \mathrm{N} ;\) (b) \(\mathrm{C}_{4} \mathrm{H}_{6} \mathrm{O} ;\) (c) \(\mathrm{C}_{9} \mathrm{H}_{15} \mathrm{ClO}\).
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