Chapter 27: Problem 2
Describe what is meant by each of the following reaction types, and illustrate with an example from the text: (a) dehydration; (b) hydrolysis; (c) solvolysis; (d) hydration of an alkene.
Chapter 27: Problem 2
Describe what is meant by each of the following reaction types, and illustrate with an example from the text: (a) dehydration; (b) hydrolysis; (c) solvolysis; (d) hydration of an alkene.
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Get started for freeDraw the structures of the products of each of the following reactions: (a) propene + hydrogen (Pt, heat) (b) 2 -butanol \(+\) heat (in the presence of sulfuric acid)
Predict the products of the monobromination of (a) \(m\) -dinitrobenzene; (b) aniline; (c) \(p\) -bromoanisole.
For the monochlorination of hydrocarbons, the following ratio of reactivities has been found: \(3^{\circ}>2^{\circ}>\) \(1^{\circ}, \quad 4.3: 3: 1 . \quad\) How many different monochloro derivatives of 2 -methylbutane are possible, and what percentage of each would you expect to find?
Write the name and structure of the benzene derivatives described below. (a) Formula: \(\mathrm{C}_{8} \mathrm{H}_{10} ;\) forms three monochlorination products when treated with \(\mathrm{Cl}_{2}\) and \(\mathrm{FeCl}_{3}\) (b) Formula: \(\mathrm{C}_{9} \mathrm{H}_{12}\); forms one monochlorination product when treated with \(\mathrm{Cl}_{2}\) and \(\mathrm{FeCl}_{3}\) (c) Formula: \(\mathrm{C}_{9} \mathrm{H}_{12}\); forms four monochlorination products when treated with \(\mathrm{Cl}_{2}\) and \(\mathrm{FeCl}_{3}\)
Predict the major organic product obtained in each of the following reactions. Assume that [O] represents \(\mathrm{Na}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\) in \(\mathrm{H}_{2} \mathrm{SO}_{4}\) (a) \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHCH}_{2} \mathrm{OH}+\mathrm{HBr} \longrightarrow\) (b) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{COH}+\mathrm{K} \longrightarrow\) (c) \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHOH} \stackrel{[\mathrm{O}]}{\longrightarrow}\) (d) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}+\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{I} \longrightarrow\)
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