The important natural sources of boron compounds are the minerals kernite, \(\mathrm{Na}_{2} \mathrm{B}_{4} \mathrm{O}_{7} \cdot 4 \mathrm{H}_{2} \mathrm{O}\) and borax, \(\mathrm{Na}_{2} \mathrm{B}_{4} \mathrm{O}_{7} \cdot 10 \mathrm{H}_{2} \mathrm{O} .\) How much additional mass of mineral must be processed per kilogram of boron obtained if the mineral is borax rather than kernite?

Short Answer

Expert verified
The additional mass of mineral that must be processed per kilogram of boron obtained if the mineral is borax rather than kernite is approximately 0.12 kg.

Step by step solution

01

Determine the Molar Mass of Boron

Firstly, use the periodic table to determine the molar mass of each element in the compounds. Boron (B) is 10.81 g/mol.
02

Calculate the molar mass of Kernite and Borax

Next, calculate the molar mass of kernite \(\mathrm{Na}_{2} \mathrm{B}_{4} \mathrm{O}_{7} \cdot 4 \mathrm{H}_{2} \mathrm{O}\) and borax \(\mathrm{Na}_{2} \mathrm{B}_{4} \mathrm{O}_{7} \cdot 10 \mathrm{H}_{2} \mathrm{O}\). For Kernite, it is (2*22.99) + (4*10.81) + (7*16.00) + (8*1.008) = 381.376 g/mol. For Borax, it is (2*22.99) + (4*10.81) + (7*16.00) + (20*1.008) = 411.376 g/mol.
03

Find the proportion of Boron

Now determine the mass fraction of boron in kernite and borax. The mass of Boron in kernite is \(4*10.81\) = 43.24 g. The mass fraction of boron in kernite is \(43.24 / 381.376\) and for borax is same, but divided by the molar mass of borax: \(43.24 / 411.376\)
04

Compare the mass needed

Finally, we will determine how much more borax is needed to yield the same amount of boron as kernite. If 1 kg of boron is obtained from kernite, the mass of borax needed will be \(1 / (43.24 / 411.376)\) kg. Then subtract the mass of kernite (1kg) to determine the additional mass needed.

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