Which of the following is a \(0.500 \mathrm{M} \mathrm{KCl}\) solution? (a) \(0.500 \mathrm{g} \mathrm{KCl} / \mathrm{mL}\) solution; (b) \(36.0 \mathrm{g} \mathrm{KCl} / \mathrm{L}\) solu- tion; (c) 7.46 mg KCl/mL solution; (d) 373 g KCl in 10.00 L solution

Short Answer

Expert verified
The 0.500 M KCl solution is option (d) - 373 g KCl in 10.00 L solution.

Step by step solution

01

Calculation for option (a)

For option (a), we are given the mass of KCl in grams per mL of solution. However, neither of these can be directly converted to moles per liter. The data makes no sense and is incorrect for a molar solution.
02

Calculation for option (b)

For option (b), we are given the mass of KCl in grams per litre. To convert this to moles per liter (i.e., molarity), we divide the mass by the molar mass of KCl (which is approximately 74.55 g/mol). That gives \((36.0 \mathrm{g} \mathrm{KCl} / \mathrm{L})/74.55 \mathrm{g/mol} = 0.483 \mathrm{M}\). Therefore, option (b) is not a 0.500 M KCl solution.
03

Calculation for option (c)

For option (c), we are given the mass of KCl in milligrams per mL of solution. We can convert milligrams to grams and mL to L to get the molarity: \((7.46 \mathrm{mg} \mathrm{KCl}/\mathrm{mL}) * \mathrm{1g/1000mg} * \mathrm{1000mL/1L} = 7.46 \mathrm{g} \mathrm{KCl} / \mathrm{L} \). Then, divide this by the molar mass of KCl (74.55 g/mol) to get the molarity: \(7.46 \mathrm{g} / 74.55 \mathrm{g/mol} = 0.100 \mathrm{M}\). Therefore, option (c) is not a 0.500 M KCl solution.
04

Calculation for option (d)

Finally, for option (d), we have 373 g of KCl in 10.00 L of solution. To get molarity, again divide the mass by the molar mass of KCl, and then by the volume of the solution in liters: \( (373 \mathrm{g} / 74.55 \mathrm{g/mol}) / 10.00 \mathrm{L} = 0.500 \mathrm{M}\). Therefore, option (d) is a 0.500 M KCl solution.

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