Chapter 4: Problem 44
What volume of \(0.750 \mathrm{M} \mathrm{AgNO}_{3}\) must be diluted with water to prepare \(250.0 \mathrm{mL}\) of \(0.425 \mathrm{M} \mathrm{AgNO}_{3} ?\)
Chapter 4: Problem 44
What volume of \(0.750 \mathrm{M} \mathrm{AgNO}_{3}\) must be diluted with water to prepare \(250.0 \mathrm{mL}\) of \(0.425 \mathrm{M} \mathrm{AgNO}_{3} ?\)
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Get started for freeCryolite, \(\mathrm{Na}_{3} \mathrm{AlF}_{6^{\prime}}\) is an important industrial reagent. It is made by the reaction below. $$\begin{array}{r} \mathrm{Al}_{2} \mathrm{O}_{3}(\mathrm{s})+6 \mathrm{NaOH}(\mathrm{aq})+12 \mathrm{HF}(\mathrm{g}) \longrightarrow 2 \mathrm{Na}_{3} \mathrm{AlF}_{6}(\mathrm{s})+9 \mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \end{array}$$ In an experiment, \(7.81 \mathrm{g} \mathrm{Al}_{2} \mathrm{O}_{3}\) and excess \(\mathrm{HF}(\mathrm{g})\) were dissolved in 3.50 L of 0.141 M NaOH. If 28.2 g \(\mathrm{Na}_{3} \mathrm{AlF}_{6}\) was obtained, then what is the percent yield for this experiment?
Excess \(\mathrm{NaHCO}_{3}\) is added to \(525 \mathrm{mL}\) of \(0.220 \mathrm{M}\) \(\mathrm{Cu}\left(\mathrm{NO}_{3}\right)_{2} .\) These substances react as follows: \(\mathrm{Cu}\left(\mathrm{NO}_{3}\right)_{2}(\mathrm{aq})+2 \mathrm{NaHCO}_{3}(\mathrm{s}) \longrightarrow\) $$ \mathrm{CuCO}_{3}(\mathrm{s})+2 \mathrm{NaNO}_{3}(\mathrm{aq})+\mathrm{H}_{2} \mathrm{O}(\mathrm{l})+\mathrm{CO}_{2}(\mathrm{g}) $$ (a) How many grams of the \(\mathrm{NaHCO}_{3}(\mathrm{s})\) will be consumed? (b) How many grams of \(\mathrm{CuCO}_{3}(\mathrm{s})\) will be produced?
The rocket boosters of the space shuttle Discovery, launched on July \(26,2005,\) used a fuel mixture containing primarily solid ammonium perchlorate, \(\mathrm{NH}_{4} \mathrm{ClO}_{4}(\mathrm{s}),\) and aluminum metal. The unbalanced chemical equation for the reaction is given below. \(\mathrm{Al}(\mathrm{s})+\mathrm{NH}_{4} \mathrm{ClO}_{4}(\mathrm{s}) \longrightarrow\) $$ \mathrm{Al}_{2} \mathrm{O}_{3}(\mathrm{s})+\mathrm{AlCl}_{3}(\mathrm{s})+\mathrm{H}_{2} \mathrm{O}(\mathrm{l})+\mathrm{N}_{2}(\mathrm{g}) $$ What is the minimum mass of \(\mathrm{NH}_{4} \mathrm{ClO}_{4}\) consumed, per kilogram of \(\mathrm{Al}\), by the reaction of \(\mathrm{NH}_{4} \mathrm{ClO}_{4}\) and Al?[Hint: Balance the elements in the order \(\mathrm{Cl}, \mathrm{H},\) \(\mathrm{O}, \mathrm{Al}, \mathrm{N} .\)]
A method for eliminating oxides of nitrogen (e.g., \(\mathrm{NO}_{2}\) ) from automobile exhaust gases is to pass the exhaust gases over solid cyanuric acid, \(\mathrm{C}_{3} \mathrm{N}_{3}(\mathrm{OH})_{3}\) When the hot exhaust gases come in contact with cyanuric acid, solid \(\mathrm{C}_{3} \mathrm{N}_{3}(\mathrm{OH})_{3}\) decomposes into isocyanic acid vapor, HNCO(g), which then reacts with \(\mathrm{NO}_{2}\) in the exhaust gases to give \(\mathrm{N}_{2}, \mathrm{CO}_{2^{\prime}}\) and \(\mathrm{H}_{2} \mathrm{O}\) How many grams of \(\mathrm{C}_{3} \mathrm{N}_{3}(\mathrm{OH})_{3}\) are needed per gram of \(\mathrm{NO}_{2}\) in this method? [Hint: To balance the equation for reaction between HNCO and \(\mathrm{NO}_{2}\), balance with respect to each kind of atom in this order: \(\mathrm{H}, \mathrm{C}, \mathrm{O}, \text { and } \mathrm{N} .]\)
Titanium tetrachloride, \(\mathrm{TiCl}_{4}\) is prepared by the reaction below. $$\begin{aligned} &3 \mathrm{TiO}_{2}(\mathrm{s})+4 \mathrm{C}(\mathrm{s})+6 \mathrm{Cl}_{2}(\mathrm{g}) \longrightarrow 3 \mathrm{TiCl}_{4}(\mathrm{g})+2 \mathrm{CO}_{2}(\mathrm{g})+2 \mathrm{CO}(\mathrm{g}) \end{aligned}$$ What is the maximum mass of \(\mathrm{TiCl}_{4}\) that can be obtained from \(35 \mathrm{g} \mathrm{TiO}_{2^{\prime}} 45 \mathrm{g} \mathrm{Cl}_{2^{\prime}}\) and \(11 \mathrm{g} \mathrm{C} ?\)
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