Chapter 5: Problem 49
What volume of \(0.0962 \mathrm{M} \mathrm{NaOH}\) is required to exactly neutralize \(10.00 \mathrm{mL}\) of \(0.128 \mathrm{M} \mathrm{HCl} ?\)
Chapter 5: Problem 49
What volume of \(0.0962 \mathrm{M} \mathrm{NaOH}\) is required to exactly neutralize \(10.00 \mathrm{mL}\) of \(0.128 \mathrm{M} \mathrm{HCl} ?\)
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Get started for freeFollowing are some laboratory methods occasionally used for the preparation of small quantities of chemicals. Write a balanced equation for each. (a) preparation of \(\mathrm{H}_{2} \mathrm{S}(\mathrm{g}): \mathrm{HCl}(\mathrm{aq})\) is heated with \(\mathrm{FeS}(\mathrm{s})\) (b) preparation of \(\mathrm{Cl}_{2}(\mathrm{g}): \mathrm{HCl}(\mathrm{aq})\) is heated with \(\mathrm{MnO}_{2}(\mathrm{s}) ; \mathrm{MnCl}_{2}(\mathrm{aq})\) and \(\mathrm{H}_{2} \mathrm{O}(1)\) are other products (c) preparation of \(\mathrm{N}_{2}: \mathrm{Br}_{2}\) and \(\mathrm{NH}_{3}\) react in aqueous solution; \(\mathrm{NH}_{4} \mathrm{Br}\) is another product (d) preparation of chlorous acid: an aqueous suspension of solid barium chlorite is treated with dilute \(\mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{aq})\)
Balance these equations for redox reactions occurring in basic solution. (a) \(\mathrm{CrO}_{4}^{2-}+\mathrm{S}_{2} \mathrm{O}_{4}^{2-} \longrightarrow \mathrm{Cr}(\mathrm{OH})_{3}(\mathrm{s})+\mathrm{SO}_{3}^{2-}\) (b) \(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-}+\mathrm{N}_{2} \mathrm{H}_{4} \longrightarrow\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{4-}+\mathrm{N}_{2}(\mathrm{g})\) (c) \(\operatorname{Fe}(\mathrm{OH})_{2}(\mathrm{s})+\mathrm{O}_{2}(\mathrm{g}) \longrightarrow \mathrm{Fe}(\mathrm{OH})_{3}(\mathrm{s})\) (d) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}+\mathrm{MnO}_{4}^{-} \longrightarrow\) \(\mathrm{CH}_{3} \mathrm{COO}^{-}+\mathrm{MnO}_{2}(\mathrm{s})\)
A \(0.4324 \mathrm{g}\) sample of a potassium hydroxide-lithium hydroxide mixture requires \(28.28 \mathrm{mL}\) of \(0.3520 \mathrm{M} \mathrm{HCl}\) for its titration to the equivalence point. What is the mass percent lithium hydroxide in this mixture?
Explain the important distinctions between (a) a strong electrolyte and strong acid; (b) an oxidizing agent and reducing agent; (c) precipitation reactions and neutralization reactions; (d) half-reaction and overall reaction.
Which aqueous solution has the greatest \(\left[\mathrm{H}^{+}\right]:\) (a) \(0.011 \mathrm{M} \mathrm{CH}_{3} \mathrm{COOH} ;\) (b) \(0.010 \mathrm{M} \mathrm{HCl} ;\) (c) \(0.010 \mathrm{M}\) \(\mathrm{H}_{2} \mathrm{SO}_{4} ;\) (d) \(1.00 \mathrm{M} \mathrm{NH}_{3} ?\) Explain your choice.
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