A 3.05 g sample of \(\mathrm{NH}_{4} \mathrm{NO}_{3}(\mathrm{s})\) is introduced into an evacuated 2.18 L flask and then heated to \(250^{\circ} \mathrm{C}\).What is the total gas pressure, in atmospheres, in the flask at \(250^{\circ} \mathrm{C}\) when the \(\mathrm{NH}_{4} \mathrm{NO}_{3}\) has completely decomposed? $$\mathrm{NH}_{4} \mathrm{NO}_{3}(\mathrm{s}) \longrightarrow \mathrm{N}_{2} \mathrm{O}(\mathrm{g})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{g})$$

Short Answer

Expert verified
The total gas pressure, in atmospheres, in the flask at \(250^{\circ} \mathrm{C}\) when the \(\mathrm{NH}_{4} \mathrm{NO}_{3}\) has completely decomposed is \(1.25 atm\).

Step by step solution

01

Finding the Number of Moles of \(\mathrm{NH}_{4} \(\mathrm{NO}_{3}\)

Begin by calculating the number of moles of the compound \(\mathrm{NH}_{4} \(\mathrm{NO}_{3}\). Molar mass of \(\mathrm{NH}_{4} \(\mathrm{NO}_{3}\) is approximately 80.052 g/mol. So, the number of moles can be calculated using the formula \(\text{Number of moles = Mass / Molar Mass}\). Upon substituting the given values, we get \(\text{Number of moles = }3.05 g /\ 80.052 g/mol = 0.0381 mol\).
02

Applying the Stoichiometry

Next, apply the stoichiometry of the reaction. The balanced chemical equation shows that 1 mole of the reactant produces 1 mole of \(\mathrm{N}_{2}\mathrm{O}(\mathrm{g})\) and 2 moles of \(\mathrm{H}_{2}\mathrm{O}(\mathrm{g})\) upon decomposition. Therefore, the total moles of gas produced = 0.0381 mol \( + 2 * 0.0381 mol = 0.1143 mol\).
03

Ideal Gas Law Calculation

Finally, use the ideal gas law equation \(P V = nRT\) to solve for the pressure. In this equation, P represents the pressure we want to determine, V is the volume which is 2.18 L, n is the number of moles calculated in the previous step, R is the gas constant which is about 0.0821 L.atm/mol.K, and T is the temperature in Kelvin, which is 250^0 C + 273 = 523 K. Substituting these values, we get \(P = nRT / V\). Thus, \(P = 0.1143 mol * 0.0821 L.atm/(mol.K) * 523 K / 2.18 L\), which gives the pressure = 1.25 atm.

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