Under the entry \(\mathrm{H}_{2} \mathrm{SO}_{4},\) a reference source lists
many values for the standard enthalpy of formation. For example, for pure
\(\mathrm{H}_{2} \mathrm{SO}_{4}(1), \Delta H_{\mathrm{f}}^{\circ}=-814.0
\mathrm{kJ} / \mathrm{mol}\)
for a solution with \(1 \mathrm{mol} \mathrm{H}_{2} \mathrm{O}\) per mole of
\(\mathrm{H}_{2} \mathrm{SO}_{4}\) \(-841.8 ;\) with \(10 \mathrm{mol}
\mathrm{H}_{2} \mathrm{O},-880.5 ;\) with \(50 \mathrm{mol} \mathrm{H}_{2}
\mathrm{O}\) \(-886.8 ;\) with \(100 \mathrm{mol} \mathrm{H}_{2} \mathrm{O},-887.7
;\) with \(500 \mathrm{mol} \mathrm{H}_{2} \mathrm{O}\) \(-890.5 ;\) with \(1000
\mathrm{mol} \mathrm{H}_{2} \mathrm{O},-892.3 ;\) with \(10,000 \mathrm{mol}\)
\(\mathrm{H}_{2} \mathrm{O},-900.8 ;\) and with \(100,000 \mathrm{mol}
\mathrm{H}_{2} \mathrm{O},-907.3\)
(a) Explain why these values are not all the same.
(b) The value of \(\Delta H_{\mathrm{f}}^{\circ}\left[\mathrm{H}_{2}
\mathrm{SO}_{4}(\mathrm{aq})\right]\) in an infinitely dilute solution is
\(-909.3 \mathrm{kJ} / \mathrm{mol} .\) What data from this chapter can you cite
to confirm this value? Explain. (c) If \(500.0 \mathrm{mL}\) of \(1.00 \mathrm{M}
\mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{aq})\) is prepared
from pure \(\mathrm{H}_{2} \mathrm{SO}_{4}(1),\) what is the approximate change
in temperature that should be observed? Assume that the \(\mathrm{H}_{2}
\mathrm{SO}_{4}(1)\) and \(\mathrm{H}_{2} \mathrm{O}(1)\) are at the same
temperature initially and that the specific heat of the \(\mathrm{H}_{2}
\mathrm{SO}_{4}(\mathrm{aq})\) is about \(4.2 \mathrm{Jg}^{-1}\) \(^{\circ}
\mathrm{C}^{-1}\).