How much energy, in kilojoules, is required to remove all the third-shell electrons in a mole of gaseous silicon atoms?

Short Answer

Expert verified
The amount of energy required to remove all third-shell electrons in a mole of gaseous silicon atoms is approximately 9.9413 kJ.

Step by step solution

01

Understand Silicon's Atomic Structure

Silicon is the 14th element in the periodic table, meaning it has 14 electrons. The electronic configuration of silicon is \(1s^2 2s^2 2p^6 3s^2 3p^2\). Therefore, it has 4 electrons in the third shell (n=3).
02

Calculate Energy for One Atom

The ionization energies for the third-shell electrons in silicon are as follows: \(E_1 = 8.1517 eV\), \(E_2 = 16.3455 eV\), \(E_3 = 33.4920 eV\), and \(E_4 = 45.1418 eV\). The energy required to remove all third shell electrons from one silicon atom would be the sum of these ionization energies, which equals \(103.130 eV\). This is in electron volts (eV), so converting to joules (J), we have \(1 eV = 1.602 \times 10^{-19} J\), therefore, the total energy required is \(103.130 eV \times 1.602 \times 10^{-19} J eV^{-1} \approx 1.65 \times 10^{-17} J\).
03

Calculate Energy for a Mole of Atoms

This was just for a single atom. We are asked to find the energy requirement for a mole of silicon atoms. Avogadro’s number tells us that \(1 mole = 6.022 \times 10^{23}\) particles, therefore, the energy required to remove all third shell electrons from a mole of silicon atoms is \(1.65 \times 10^{-17} J \times 6.022 \times 10^{23} mole^{-1} = 9941.3 J/mole = 9.9413 kJ/mole\).

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