Chapter 10: Problem 1
How is the geometry of a molecule defined and why is the study of molecular geometry important?
Chapter 10: Problem 1
How is the geometry of a molecule defined and why is the study of molecular geometry important?
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Get started for freeAssume that the third-period element phosphorus forms a diatomic molecule, \(\mathrm{P}_{2}\), in an analogous way as nitrogen does to form \(\mathrm{N}_{2}\). (a) Write the electronic configuration for \(\mathrm{P}_{2}\). Use \(\left[\mathrm{Ne}_{2}\right]\) to represent the electron configuration for the first two periods. (b) Calculate its bond order. (c) What are its magnetic properties (diamagnetic or paramagnetic)?
Use molecular orbital theory to explain why the \(\mathrm{Be}_{2}\) molecule does not exist
Specify which hybrid orbitals are used by carbon atoms in these species: (a) \(\mathrm{CO},\) (b) \(\mathrm{CO}_{2},\) (c) \(\mathrm{CN}^{-}\).
Draw Lewis structures and give the other information requested for these: (a) \(\mathrm{SO}_{3}\). Polar or nonpolar molecule? (b) \(\mathrm{PF}_{3}\). Polar or nonpolar molecule? (c) \(\mathrm{F}_{3} \mathrm{SiH} .\) Show the direction of the resultant dipole moment. (d) \(\mathrm{SiH}_{3}^{-}\). Planar or pyramidal shape? (e) \(\mathrm{Br}_{2} \mathrm{CH}_{2} .\) Polar or nonpolar molecule?
Compare the relative stability of these species and indicate their magnetic properties (that is, diamagnetic or paramagnetic): \(\mathrm{O}_{2}, \mathrm{O}_{2}^{+}, \mathrm{O}_{2}^{-}\) (superoxide ion), \(\mathrm{O}_{2}^{2-}\) (peroxide ion).
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