Chapter 10: Problem 46
Explain the significance of bond order. Can bond order be used for quantitative comparisons of the strengths of chemical bonds?
Chapter 10: Problem 46
Explain the significance of bond order. Can bond order be used for quantitative comparisons of the strengths of chemical bonds?
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Get started for freeDefine these terms: bonding molecular orbital, antibonding molecular orbital, pi molecular orbital, sigma molecular orbital.
Use molecular orbital theory to explain why the \(\mathrm{Be}_{2}\) molecule does not exist
The formation of \(\mathrm{H}^{+}\) from two \(\mathrm{H}\) atoms is an energetically favorable process. Yet statistically there is less than a 100 percent chance that any two \(\mathrm{H}\) atoms will undergo the reaction. Apart from energy considerations, how would you account for this observation based on the electron spins in the two \(\mathrm{H}\) atoms?
The compound 1,2 -dichloroethane \(\left(\mathrm{C}_{2} \mathrm{H}_{4} \mathrm{Cl}_{2}\right)\) is nonpolar, while cis-dichloroethylene \(\left(\mathrm{C}_{2} \mathrm{H}_{2} \mathrm{Cl}_{2}\right)\) has a dipole moment: The reason for the difference is that groups connected by a single bond can rotate with respect to each other, but no rotation occurs when a double bond connects the groups. On the basis of bonding considerations, explain why rotation occurs in \(1,2-\) dichloroethane but not in \(c i s\) -dichloroethylene.
What is molecular orbital theory? How does it differ from valence bond theory?
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