Chapter 11: Problem 43
What factor determines whether a carbon atom in a compound is asymmetric?
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 11: Problem 43
What factor determines whether a carbon atom in a compound is asymmetric?
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeDraw Newman projections of the staggered and eclipsed conformations of propane. Rank them in stability.
Amines are Bronsted bases. The unpleasant smell of fish is due to the presence of certain amines. Explain why cooks often add lemon juice to suppress the odor of fish (in addition to enhancing the flavor).
Generally aldehydes are more susceptible to oxidation in air than are ketones. Use acetaldehyde and acetone as examples and show why ketones such as acetone are more stable than aldehydes in this respect.
Name the classes to which these compounds belong: (a) \(\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{OH}\) (b) \(\mathrm{CH}_{3} \mathrm{OC}_{2} \mathrm{H}_{5}\) (c) \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CHO}\) (d) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{COOH}\) (e) \(\mathrm{CH}_{3} \mathrm{NH}_{2}\)
The combustion of \(20.63 \mathrm{mg}\) of compound \(\mathrm{Y}\), which contains only \(\mathrm{C}, \mathrm{H},\) and \(\mathrm{O}\), with excess oxygen gave \(57.94 \mathrm{mg}\) of \(\mathrm{CO}_{2}\) and \(11.85 \mathrm{mg}\) of \(\mathrm{H}_{2} \mathrm{O}\). (a) Calculate how many milligrams of \(\mathrm{C}, \mathrm{H},\) and \(\mathrm{O}\) were present in the original sample of \(Y\). (b) Derive the empirical formula of Y. (c) Suggest a plausible structure for \(\mathrm{Y}\) if the empirical formula is the same as the molecular formula.
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