Chapter 11: Problem 63
Draw structures for these compounds: (a) cyclopentane, \((\) b) \(c i s-2\) -butene, \((\) c) 2 -hexanol, (d) 1,4 -dibromobenzene, (e) 2 -butyne.
Chapter 11: Problem 63
Draw structures for these compounds: (a) cyclopentane, \((\) b) \(c i s-2\) -butene, \((\) c) 2 -hexanol, (d) 1,4 -dibromobenzene, (e) 2 -butyne.
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Get started for freeDraw the structures of \(c i s-2\) -butene and trans-2butene. Which of the two compounds would give off more heat on hydrogenation to butane? Explain.
Suppose benzene contained three distinct single bonds and three distinct double bonds. How many different structural isomers would there be for dichlorobenzene \(\left(\mathrm{C}_{6} \mathrm{H}_{4} \mathrm{Cl}_{2}\right)\) ? Draw all your proposed structures.
Write the structural formula of an aldehyde that is an isomer of acetone.
Octane number is assigned to gasoline to indicate the tendency of "knocking" in the automobile's engine. The higher the octane number, the more smoothly the fuel will burn without knocking. Branched-chain aliphatic hydrocarbons have higher octane numbers than straight-chain aliphatic hydrocarbons, and aromatic hydrocarbons have the highest octane numbers. (a) Arrange these compounds in the order of decreasing octane numbers: \(2,2,4-\) trimethylpentane, toluene (methylbenzene), \(n\) -heptane, and 2 -methylhexane. (b) Oil refineries carry out catalytic reforming in which a straight-chain hydrocarbon, in the presence of a catalyst, is converted to an aromatic molecule and a useful by-product. Write an equation for the conversion from \(n\) -heptane to toluene. (c) Until 2000 , tert-butylmethyl ether had been widely used as an antiknocking agent to enhance the octane number of gasoline. Write the structural formula of the compound.
2-Butanone can be reduced to 2 -butanol by reagents such as lithium aluminum hydride \(\left(\mathrm{LiAlH}_{4}\right)\). (a) Write the formula of the product. Is it chiral? (b) In reality, the product does not exhibit optical activity. Explain.
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