Chapter 12: Problem 76
Freeze-dried coffee is prepared by freezing a sample of brewed coffee and then removing the ice component by vacuum-pumping the sample. Describe the phase changes taking place during these processes.
Chapter 12: Problem 76
Freeze-dried coffee is prepared by freezing a sample of brewed coffee and then removing the ice component by vacuum-pumping the sample. Describe the phase changes taking place during these processes.
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Get started for freeExplain in terms of intermolecular forces why (a) \(\mathrm{NH}_{3}\) has a higher boiling point than \(\mathrm{CH}_{4}\) and \((\mathrm{b}) \mathrm{KCl}\) has a higher melting point than \(\mathrm{I}_{2}\).
Crystalline silicon has a cubic structure. The unit cell edge length is \(543 \mathrm{pm}\). The density of the solid is \(2.33 \mathrm{~g} / \mathrm{cm}^{3}\). Calculate the number of \(\mathrm{Si}\) atoms in one unit cell.
The molar heats of fusion and sublimation of molecular iodine are \(15.27 \mathrm{~kJ} / \mathrm{mol}\) and \(62.30 \mathrm{~kJ} / \mathrm{mol}\), respectively. Estimate the molar heat of vaporization of liquid iodine.
Vapor pressure measurements at several different temperatures are shown here for mercury. Determine graphically the molar heat of vaporization for mercury. \(\begin{array}{cccccc}t\left({ }^{\circ} \mathrm{C}\right) & 200 & 250 & 300 & 320 & 340 \\ P(\mathrm{mmHg}) & 17.3 & 74.4 & 246.8 & 376.3 & 557.9\end{array}\)
A solid is hard, brittle, and electrically nonconducting. Its melt (the liquid form of the substance) and an aqueous solution containing the substance do conduct electricity. Classify the solid.
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