Chapter 13: Problem 4
As you know, some solution processes are endothermic and others are exothermic. Provide a molecular interpretation for the difference.
Chapter 13: Problem 4
As you know, some solution processes are endothermic and others are exothermic. Provide a molecular interpretation for the difference.
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Get started for freeA mixture of liquids \(A\) and \(B\) exhibits ideal behavior. At \(84^{\circ} \mathrm{C},\) the total vapor pressure of a solution containing 1.2 moles of \(A\) and 2,3 moles of \(B\) is 331 \(\mathrm{mmHg}\). Upon the addition of another mole of \(\mathrm{B}\) to the solution, the vapor pressure increases to 347 \(\mathrm{mmHg}\). Calculate the vapor pressures of pure \(\mathrm{A}\) and \(\mathrm{B}\) at \(84^{\circ} \mathrm{C}\)
Pheromones are compounds secreted by the females of many insect species to attract males. One of these compounds contains \(80.78 \%\) C, \(13.56 \% \mathrm{H}\), and \(5.66 \%\) O. A solution of \(1.00 \mathrm{~g}\) of this pheromone in \(8.50 \mathrm{~g}\) of benzene freezes at \(3.37^{\circ} \mathrm{C}\). What are the molecular formula and molar mass of the compound? (The normal freezing point of pure benzene is \(5.50^{\circ} \mathrm{C}\) ).
A mixture of \(\mathrm{NaCl}\) and sucrose \(\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right)\) of combined mass \(10.2 \mathrm{~g}\) is dissolved in enough water to make up a \(250 \mathrm{~mL}\) solution. The osmotic pressure of the solution is \(7.32 \mathrm{~atm}\) at \(23^{\circ} \mathrm{C}\). Calculate the mass percent of \(\mathrm{NaCl}\) in the mixture.
Briefly describe the solution process at the molecular level. Use the dissolution of a solid in a liquid as an example.
The alcohol content of hard liquor is normally given in terms of the "proof," which is defined as twice the percentage by volume of ethanol \(\left(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\right)\) present. Calculate the number of grams of alcohol present in \(1.00 \mathrm{~L}\) of 75 proof gin. The density of ethanol is \(0.798 \mathrm{~g} / \mathrm{mL}\)
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