Chapter 14: Problem 49
How does a catalyst increase the rate of a reaction?
Chapter 14: Problem 49
How does a catalyst increase the rate of a reaction?
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Get started for freeConsider the reaction $$ X+Y \longrightarrow Z $$ These data are obtained at \(360 \mathrm{~K}\): $$ \begin{aligned} &\text { Initial Rate of }\\\ &\begin{array}{ccc} \text { Disappearance of } \mathrm{X}(\mathrm{M} / \mathrm{s}) & {[\mathrm{X}]} & {[\mathrm{Y}]} \\ \hline 0.147 & 0.10 & 0.50 \\ 0.127 & 0.20 & 0.30 \\ 4.064 & 0.40 & 0.60 \\ 1.016 & 0.20 & 0.60 \\ 0.508 & 0.40 & 0.30 \end{array} \end{aligned} $$ (a) Determine the order of the reaction. (b) Determine the initial rate of disappearance of \(X\) when the concentration of \(\mathrm{X}\) is \(0.30 \mathrm{M}\) and that of \(\mathrm{Y}\) is \(0.40 \mathrm{M}\)
Consider the zero-order reaction \(\mathrm{A} \longrightarrow\) product. (a) Write the rate law for the reaction. (b) What are the units for the rate constant? (c) Plot the rate of the reaction versus [A].
Most reactions, including enzyme-catalyzed reactions, proceed faster at higher temperatures. However, for a given enzyme, the rate drops off abruptly at a certain temperature. Account for this behavior.
Define activation energy. What role does activation energy play in chemical kinetics?
What is meant by the order of a reaction?
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