Chapter 16: Problem 65
Define salt hydrolysis. Categorize salts according to how they affect the \(\mathrm{pH}\) of a solution.
Chapter 16: Problem 65
Define salt hydrolysis. Categorize salts according to how they affect the \(\mathrm{pH}\) of a solution.
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Get started for freeWrite an equation relating \(\left[\mathrm{H}^{+}\right]\) and \(\left[\mathrm{OH}^{-}\right]\) in solution at \(25^{\circ} \mathrm{C}\).
Classify each of these species as a Bronsted acid or base, or both: (a) \(\mathrm{H}_{2} \mathrm{O},\) (b) \(\mathrm{OH}^{-},\) (c) \(\mathrm{H}_{3} \mathrm{O}^{+}\), (d) \(\mathrm{NH}_{3}\) (e) \(\mathrm{NH}_{4}^{+},\) (f) \(\mathrm{NH}_{2}^{-},(\mathrm{g}) \mathrm{NO}_{3}^{-},\) (h) \(\mathrm{CO}_{3}^{2-}\) (i) HBr, (j) HCN.
Complete this table for a solution: $$\begin{array}{c|c|c}\mathrm{pH} & {\left[\mathrm{H}^{+}\right]} & \text {Solution is } \\\\\hline<7 & & \\\\\hline & <1.0 \times 10^{-7} M & \\\\\hline & & \text { Neutral }\end{array}$$
Calculate the \(\mathrm{pH}\) of a solution that is \(1.00 \mathrm{M} \mathrm{HCN}\) and \(1.00 M\) HF. Compare the concentration (in molarity) of the \(\mathrm{CN}^{-}\) ion in this solution with that in a \(1.00 \mathrm{M}\) HCN solution. Comment on the difference.
Most of the hydrides of Group \(1 \mathrm{~A}\) and Group \(2 \mathrm{~A}\) metals are ionic (the exceptions are \(\mathrm{BeH}_{2}\) and \(\mathrm{MgH}_{2}\), which are covalent compounds). (a) Describe the reaction between the hydride ion \(\left(\mathrm{H}^{-}\right)\) and water in terms of a Bronsted acid-base reaction. (b) The same reaction can also be classified as a redox reaction. Identify the oxidizing and reducing agents.
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