Chapter 19: Problem 39
Steel hardware, including nuts and bolts, is often coated with a thin plating of cadmium. Explain the function of the cadmium layer.
Chapter 19: Problem 39
Steel hardware, including nuts and bolts, is often coated with a thin plating of cadmium. Explain the function of the cadmium layer.
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Which species in each pair is a better reducing agent under standard-state conditions? (a) \(\mathrm{Na}\) or \(\mathrm{Li},\) (b) \(\mathrm{H}_{2}\) or \(\mathrm{I}_{2},\) (c) \(\mathrm{Fe}^{2+}\) or \(\mathrm{Ag}\), (d) \(\mathrm{Br}^{-}\) or \(\mathrm{Co}^{2+}\).
Given the following standard reduction potentials, calculate the ion-product, \(K_{\mathrm{w}},\) for water at \(25^{\circ} \mathrm{C}\) : \(2 \mathrm{H}^{+}(a q)+2 e^{-} \longrightarrow \mathrm{H}_{2}(g) \quad E^{\circ}=0.00 \mathrm{~V}\) \(2 \mathrm{H}_{2} \mathrm{O}(l)+2 e^{-} \longrightarrow \mathrm{H}_{2}(g)+2 \mathrm{OH}^{-}(a q)\) $$ E^{\circ}=-0.83 \mathrm{~V} $$
Explain why chlorine gas can be prepared by electrolyzing an aqueous solution of \(\mathrm{NaCl}\) but fluorine gas cannot be prepared by electrolyzing an aqueous solution of NaF.
A galvanic cell using \(\mathrm{Mg} / \mathrm{Mg}^{2+}\) and \(\mathrm{Cu} / \mathrm{Cu}^{2+}\) half-cell's operates under standard-state conditions at \(25^{\circ} \mathrm{C}\) and each compartment has a volume of \(218 \mathrm{~mL}\). The cell delivers 0.22 A for \(31.6 \mathrm{~h}\). (a) How many grams of \(\mathrm{Cu}\) are deposited? (b) What is the \(\left[\mathrm{Cu}^{2+}\right]\) remaining?
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