Chapter 20: Problem 9
Define the following terms: coordination compound, ligand, donor atom, coordination number, chelating agent.
Chapter 20: Problem 9
Define the following terms: coordination compound, ligand, donor atom, coordination number, chelating agent.
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Get started for freeCompounds containing the \(\mathrm{Sc}^{3+}\) ion are colorless, whereas those containing the \(\mathrm{Ti}^{3+}\) ion are colored. Explain.
Write the electron configurations of these ions: \(\mathrm{V}^{5+}\) \(\mathrm{Cr}^{3+}, \mathrm{Mn}^{2+}, \mathrm{Fe}^{3+}, \mathrm{Cu}^{2+}, \mathrm{Sc}^{3+}, \mathrm{T}_{1}^{4+}\)
Explain these facts: (a) Copper and iron have several oxidation states, whereas zinc exists in only one. (b) Copper and iron form colored ions, whereas zinc does not
A student in 1895 prepared three chromium coordination compounds having the same formulas of \(\mathrm{CrCl}_{3}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\) with these properties: Write modern formulas for these compounds and suggest a method for confirming the number of \(\mathrm{Cl}^{-}\) ions present in solution in each case. (Hint: Some of the compounds may exist as hydrates, which are compounds that have a specific number of water molecules attached to them. The \(\mathrm{Cr}\) has a coordination number of 6 in all three compounds.)
Write the formulas for each of these ions and compounds: (a) bis(ethylenediamine) dichlorochro\(\operatorname{mium}(\mathrm{III})\) (b) pentacarbonyliron(0), (c) potassium tetracyanocuprate(II), (d) tetraammineaquochlorocobalt(III) chloride.
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