Chapter 22: Problem 25
What are Chargaff's rules?
Chapter 22: Problem 25
What are Chargaff's rules?
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Get started for freeDraw the structures of the dipeptides that can be formed from the reaction between the amino acids glycine and alanine.
How many different tripeptides can be formed by lysine and alanine?
Consider the formation of a dimeric protein $$ 2 \mathrm{P} \longrightarrow \mathrm{P}_{2} $$ At \(25^{\circ} \mathrm{C},\) we have \(\Delta H^{\circ}=17 \mathrm{~kJ} / \mathrm{mol}\) and \(\Delta S^{\circ}=\) \(65 \mathrm{~J} / \mathrm{K} \cdot \mathrm{mol}\). Is the dimerization favored at this temperature? Comment on the effect of lowering the temperature. Does your result explain why some enzymes lose their activities under cold conditions?
Proteins vary widely in structure, whereas nucleic acids have rather uniform structures. How do you account for this major difference?
In Chapter 13 you learned about the colligative properties of solutions. Which of the colligative properties is suitable for determining the molar mass of a polymer? Why?
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