Heating \(2.40 \mathrm{~g}\) of the oxide of metal \(\mathrm{X}\) (molar mass of \(X=55.9 \mathrm{~g} / \mathrm{mol}\) ) in carbon monoxide \((\mathrm{CO})\) yields the pure metal and carbon dioxide. The mass of the metal product is \(1.68 \mathrm{~g}\). From the data given, show that the simplest formula of the oxide is \(\mathrm{X}_{2} \mathrm{O}_{3}\) and write a balanced equation for the reaction.

Short Answer

Expert verified
The simplest formula of the oxide is \(\mathrm{X}_{2}\mathrm{O}_{3}\) and the balanced equation for the reaction is \[ \mathrm{X}_{2}\mathrm{O}_{3}(s) + 3\mathrm{CO}(g) \rightarrow 2\mathrm{X}(s) +3 \mathrm{CO}_{2}(g)\]

Step by step solution

01

Calculating moles of the pure metal X

We calculate the moles of the metal X by using the given mass and its molar mass, using the formula \[ \text{Number of moles} = \frac{\text{mass}}{\text{molar mass}} \] Hence, the moles of the pure metal X is \[ \text{moles(X)} = \frac{1.68 \, g}{55.9 \, g/mol} = 0.03003 \, mol \] rounding to \(3.0 \times {10}^{-2} \, mol\] for three significant figures.
02

Calculating mass of Oxygen

Subtract the mass of the pure metal X from the mass of the compound to find the mass of Oxygen. \[ \text{Oxygen mass (O)} = \text{mass of compound} - \text{mass of X} = 2.40 \, g - 1.68 \, g = 0.72 \, g\]
03

Calculating moles of Oxygen

We calculate moles of oxygen using the molar mass of oxygen which is \(16.00 \, g/mol\). Thus, \[ \text{moles(O)} = \frac{0.72 \, g}{16.00 \, g/mol} = 0.045 mol\] rounding to \(4.5 \times {10}^{-2} \, mol\) for three significant figures.
04

Deriving the ratio of moles of X to O

By calculating the ratio of moles of X to O, we can deduce the formula of the compound. We divide the larger moles by the smaller one to get a whole number. Hence, we get a ratio of \(1.5:1\) for \(X:O\), which simplifies to \(3:2\) or \(\mathrm{X}_{2}\mathrm{O}_{3}\),
05

Balancing the Equation

Since the smallest formula of the oxide compound is \(\mathrm{X}_{2}\mathrm{O}_{3}\) and X was originally combined with CO, the balanced equation is, \[ \mathrm{X}_{2}\mathrm{O}_{3}(s) + 3\mathrm{CO}(g) \rightarrow 2\mathrm{X}(s) +3 \mathrm{CO}_{2}(g)\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass
Understanding molar mass is crucial to mastering stoichiometry, which is the calculation of quantities in chemical reactions. The molar mass of a substance is the mass of one mole of that substance. It serves as a bridge between the microscopic world of atoms and molecules and the macroscopic world we observe.

For instance, in the given exercise, the molar mass of metal X is specified as 55.9 g/mol. This means each mole of metal X weighs 55.9 grams. By dividing the mass of the element by its molar mass, we find how many moles we have, which is the first step in many stoichiometry calculations. This molar mass led us to calculate the moles of metal X present in the sample, further allowing us to delve into the stoichiometric conversions involved in determining the empirical formula.
Chemical Reaction Balancing
Balancing chemical reactions is a fundamental skill in chemistry that ensures the law of conservation of mass is respected. In other words, the number of atoms of each element must be the same on both sides of the reaction equation. To balance a reaction, coefficients are added in front of the chemical formulas to adjust the number of atoms or molecules.

In the solution provided, after determining the empirical formula of the oxide of metal X, the reaction is then balanced. The final step illustrates that for every one mole of the compound \( \mathrm{X}_{2}\mathrm{O}_{3} \), three moles of carbon monoxide \( \mathrm{CO} \) react to produce two moles of the metal X and three moles of carbon dioxide \( \mathrm{CO}_{2} \). This balanced equation provides a macroscopic view of the proportions in which reactants combine to form products.
Mole-to-Mole Ratio
The mole-to-mole ratio is derived from a balanced chemical equation and indicates the proportion of reactants that react and the products formed. It is a critical aspect of stoichiometry as it allows for the conversion between moles of different substances in a chemical reaction.

In the given exercise, once the moles of metal X and oxygen are determined, we used the mole-to-mole ratio to find the composition of the metal oxide. By simplifying the ratio of the moles of X to O (1.5:1), we identified the empirical formula, revealing that two moles of metal X react with three moles of oxygen atoms to form the oxide \( \mathrm{X}_{2}\mathrm{O}_{3} \). Therefore, we can infer the stoichiometric relationship in the compound and the reacting gases for the balanced equation.
Empirical Formula Calculation
The empirical formula represents the simplest whole-number ratio of the elements in a compound. Calculating the empirical formula involves determining the molar ratio of the elements present, using the mass and molar mass to find the number of moles.

In the context of the exercise, once we have the number of moles of metal X and oxygen, the empirical formula of the oxide is deduced by finding the simplest whole-number ratio of moles of metal X to moles of oxygen. The calculated moles lead to a mole ratio of 1.5:1 (or simplified to 3:2), indicating the empirical formula \( \mathrm{X}_{2}\mathrm{O}_{3} \). This process provides the foundation for stoichiometric calculations in chemistry, allowing the prediction of quantities required and produced in a given reaction.

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Most popular questions from this chapter

Each copper(II) sulfate unit is associated with five water molecules in crystalline copper(II) sulfate pentahydrate \(\left(\mathrm{CuSO}_{4} \cdot 5 \mathrm{H}_{2} \mathrm{O}\right)\). When this compound is heated in air above \(100^{\circ} \mathrm{C},\) it loses the water molecules and also its blue color: $$ \mathrm{CuSO}_{4} \cdot 5 \mathrm{H}_{2} \mathrm{O} \longrightarrow \mathrm{CuSO}_{4}+5 \mathrm{H}_{2} \mathrm{O} $$ If \(9.60 \mathrm{~g}\) of \(\mathrm{CuSO}_{4}\) are left after heating \(15.01 \mathrm{~g}\) of the blue compound, calculate the number of moles of \(\mathrm{H}_{2} \mathrm{O}\) originally present in the compound.

How many moles of cobalt (Co) atoms are there in \(6.00 \times 10^{9}(6\) billion) Co atoms?

The depletion of ozone \(\left(\mathrm{O}_{3}\right)\) in the stratosphere has been a matter of great concern among scientists in recent years. It is believed that ozone can react with nitric oxide (NO) that is discharged from the high-altitude jet plane, the SST. The reaction is $$ \mathrm{O}_{3}+\mathrm{NO} \longrightarrow \mathrm{O}_{2}+\mathrm{NO}_{2} $$ If \(0.740 \mathrm{~g}\) of \(\mathrm{O}_{3}\) reacts with \(0.670 \mathrm{~g}\) of \(\mathrm{NO}\), how many grams of \(\mathrm{NO}_{2}\) will be produced? Which compound is the limiting reagent? Calculate the number of moles of the excess reagent remaining at the end of the reaction.

Fermentation is a complex chemical process of wine making in which glucose is converted into ethanol and carbon dioxide: $$ \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6} \longrightarrow 2 \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}+2 \mathrm{CO}_{2} $$ glucose ethanol Starting with \(500.4 \mathrm{~g}\) of glucose, what is the maximum amount of ethanol in grams and in liters that can be obtained by this process? (Density of ethanol = \(0.789 \mathrm{~g} / \mathrm{mL} .)\)

Urea \(\left[\left(\mathrm{NH}_{2}\right)_{2} \mathrm{CO}\right]\) is used for fertilizer and many other things. Calculate the number of \(\mathrm{N}, \mathrm{C}, \mathrm{O},\) and \(\mathrm{H}\) atoms in \(1.68 \times 10^{4} \mathrm{~g}\) of urea.

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