For the complete redox reactions given here, write the half-reactions and identify the oxidizing and reducing agents: (a) \(4 \mathrm{Fe}+3 \mathrm{O}_{2} \longrightarrow 2 \mathrm{Fe}_{2} \mathrm{O}_{3}\) (b) \(\mathrm{Cl}_{2}+2 \mathrm{NaBr} \longrightarrow 2 \mathrm{NaCl}+\mathrm{Br}_{2}\) (c) \(\mathrm{Si}+2 \mathrm{~F}_{2} \longrightarrow \mathrm{SiF}_{4}\) (d) \(\mathrm{H}_{2}+\mathrm{Cl}_{2} \longrightarrow 2 \mathrm{HCl}\)

Short Answer

Expert verified
(a) Oxidizing agent: O2, Reducing agent: Fe \n (b) Oxidizing agent: Cl2, Reducing agent: Br- \n (c) Oxidizing agent: F2, Reducing agent: Si \n (d) Oxidizing agent: Cl2, Reducing agent: H2

Step by step solution

01

Identify oxidation and reduction

A substance is being oxidized if it loses electrons and being reduced if it gains electrons. In (a), Fe loses electrons and changes to Fe2+ (thus being oxidized), while O2 gains electrons and changes to O2- (thus being reduced). In (b), Cl2 gains electrons and changes to Cl- (thus being reduced), while Br- loses electrons and changes to Br2 (thus being oxidized). Similar process for (c) and (d).
02

Write half-reactions

(a) Oxidation: \(4Fe \rightarrow 4Fe^{2+} + 8e^{-}\), Reduction: \(3O_{2} + 12e^{-} \rightarrow 6O^{2-}\) \n (b) Oxidation: \(2Br^{-} \rightarrow Br2 + 2e^{-}\), Reduction: \(Cl2 + 2e^{-} \rightarrow 2Cl^{-}\) \n (c) Oxidation: \(\mathrm{Si} \rightarrow \mathrm{Si^{4+}} + 4e^{-}\), Reduction: \(\mathrm{2F2} + 8e^{-} \rightarrow 4F^{-}\) \n (d) Oxidation: \(\mathrm{H2} \rightarrow 2H^{+} + 2e^{-}\), Reduction: \(\mathrm{Cl2} + 2e^{-} \rightarrow 2Cl^{-}\)
03

Identify oxidizing and reducing agents

The oxidizing agent is the substance that is reduced, while the reducing agent is the substance that is oxidized. (a) Oxidizing agent: O2, Reducing agent: Fe \n (b) Oxidizing agent: Cl2, Reducing agent: Br- \n (c) Oxidizing agent: F2, Reducing agent: Si \n (d) Oxidizing agent: Cl2, Reducing agent: H2

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