Chapter 6: Problem 4
A truck initially traveling at \(60 \mathrm{~km}\) per hour is brought to a complete stop at a traffic light. Does this change violate the law of conservation of energy? Explain.
Chapter 6: Problem 4
A truck initially traveling at \(60 \mathrm{~km}\) per hour is brought to a complete stop at a traffic light. Does this change violate the law of conservation of energy? Explain.
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Get started for freeConstruct a table with the headings \(q, w, \Delta E,\) and \(\Delta H .\) For each of the following processes, deduce whether each of the quantities listed is positive \((+)\) negative \((-),\) or zero (0) . (a) Freezing of benzene. (b) Compression of an ideal gas at constant temperature. (c) Reaction of sodium with water. (d) Boiling liquid ammonia. (e) Heating a gas at constant volume. (f) Melting of ice.
When \(1.034 \mathrm{~g}\) of naphthalene \(\left(\mathrm{C}_{10} \mathrm{H}_{8}\right)\) are burned in a constant-volume bomb calorimeter at \(298 \mathrm{~K}, 41.56 \mathrm{~kJ}\) of heat are evolved. Calculate \(\Delta E\) and \(\Delta H\) for the reaction on a molar basis.
A 44.0-g sample of an unknown metal at \(99.0^{\circ} \mathrm{C}\) was placed in a constant-pressure calorimeter containing \(80.0 \mathrm{~g}\) of water at \(24.0^{\circ} \mathrm{C}\). The final temperature of the system was found to be \(28.4^{\circ} \mathrm{C}\). Calculate the specific heat of the metal. (The heat capacity of the calorimeter is \(\left.12.4 \mathrm{~J} /{ }^{\circ} \mathrm{C} .\right)\)
A quantity of 0.020 mole of a gas initially at \(0.050 \mathrm{~L}\) and \(20^{\circ} \mathrm{C}\) undergoes a constant-temperature expansion until its volume is \(0.50 \mathrm{~L}\). Calculate the work done (in joules) by the gas if it expands (a) against a vacuum and (b) against a constant pressure of 0.20 atm. (c) If the gas in (b) is allowed to expand unchecked until its pressure is equal to the external pressure, what would its final volume be before it stopped expanding, and what would be the work done?
Which of the following standard enthalpy of formation values is not zero at \(25^{\circ} \mathrm{C} ? \mathrm{Na}(s), \mathrm{Ne}(g)\) \(\mathrm{CH}_{4}(g), \mathrm{S}_{8}(s), \mathrm{Hg}(l), \mathrm{H}(g)\)
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