Chapter 6: Problem 5
These are various forms of energy: chemical, heat, light, mechanical, and electrical. Suggest ways of interconverting these forms of energy.
Chapter 6: Problem 5
These are various forms of energy: chemical, heat, light, mechanical, and electrical. Suggest ways of interconverting these forms of energy.
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Get started for freeWhich of the following standard enthalpy of formation values is not zero at \(25^{\circ} \mathrm{C} ? \mathrm{Na}(s), \mathrm{Ne}(g)\) \(\mathrm{CH}_{4}(g), \mathrm{S}_{8}(s), \mathrm{Hg}(l), \mathrm{H}(g)\)
The convention of arbitrarily assigning a zero enthalpy value for the most stable form of each element in the standard state at \(25^{\circ} \mathrm{C}\) is a convenient way of dealing with enthalpies of reactions. Explain why this convention cannot be applied to nuclear reactions.
Lime is a term that includes calcium oxide \((\mathrm{CaO}\) also called quicklime) and calcium hydroxide \(\left[\mathrm{Ca}(\mathrm{OH})_{2},\right.\) also called slaked lime \(] .\) It is used in the steel industry to remove acidic impurities, in airpollution control to remove acidic oxides such as \(\mathrm{SO}_{2}\), and in water treatment. Quicklime is made industrially by heating limestone \(\left(\mathrm{CaCO}_{3}\right)\) above \(2000^{\circ} \mathrm{C}\) : $$ \begin{aligned} \mathrm{CaCO}_{3}(s) \longrightarrow \mathrm{CaO}(s)+\mathrm{CO}_{2}(g) \\ \Delta H^{\circ} &=177.8 \mathrm{~kJ} / \mathrm{mol} \end{aligned} $$ Slaked lime is produced by treating quicklime with water: $$ \begin{aligned} \mathrm{CaO}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Ca}(\mathrm{OH})_{2}(s) \\ \Delta H^{\circ} &=-65.2 \mathrm{~kJ} / \mathrm{mol} \end{aligned} $$ The exothermic reaction of quicklime with water and the rather small specific heats of both quicklime \(\left(0.946 \mathrm{~J} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C}\right)\) and slaked lime \(\left(1.20 \mathrm{~J} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C}\right)\) make it hazardous to store and transport lime in vessels made of wood. Wooden sailing ships carrying lime would occasionally catch fire when water leaked into the hold. (a) If a 500 -g sample of water reacts with an equimolar amount of \(\mathrm{CaO}\) (both at an initial temperature of \(\left.25^{\circ} \mathrm{C}\right)\), what is the final temperature of the product, \(\mathrm{Ca}(\mathrm{OH})_{2} ?\) Assume that the product absorbs all of the heat released in the reaction. (b) Given that the standard enthalpies of formation of \(\mathrm{CaO}\) and \(\mathrm{H}_{2} \mathrm{O}\) are \(-635.6 \mathrm{~kJ} / \mathrm{mol}\) and \(-285.8 \mathrm{~kJ} / \mathrm{mol}\), respectively, cal- culate the standard enthalpy of formation of \(\mathrm{Ca}(\mathrm{OH})_{2}\).
Describe two exothermic processes and two endothermic processes.
Describe the interconversions of forms of energy occurring in these processes: (a) You throw a softball up into the air and catch it. (b) You switch on a flashlight. (c) You ride the ski lift to the top of the hill and then ski down. (d) You strike a match and let it burn down.
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