Chapter 6: Problem 79
If energy is conserved, how can there be an energy cricis?
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 6: Problem 79
If energy is conserved, how can there be an energy cricis?
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeExplain what is meant by a state function. Give two examples of quantities that are state functions and two that are not.
Consider the reaction $$ \begin{aligned} \mathrm{N}_{2}(g)+3 \mathrm{H}_{2}(g) \longrightarrow & 2 \mathrm{NH}_{3}(g) \\\ \Delta H_{\mathrm{rxn}}^{\circ} &=-92.6 \mathrm{~kJ} / \mathrm{mol} \end{aligned} $$ If 2.0 moles of \(\mathrm{N}_{2}\) react with 6.0 moles of \(\mathrm{H}_{2}\) to form \(\mathrm{NH}_{3},\) calculate the work done (in joules) against a pressure of 1.0 atm at \(25^{\circ} \mathrm{C}\). What is \(\Delta E\) for this reaction? Assume the reaction goes to completion.
The work done to compress a gas is \(74 \mathrm{~J}\). As a result, \(26 \mathrm{~J}\) of heat is given off to the surroundings. Calculate the change in energy of the gas.
Construct a table with the headings \(q, w, \Delta E,\) and \(\Delta H .\) For each of the following processes, deduce whether each of the quantities listed is positive \((+)\) negative \((-),\) or zero (0) . (a) Freezing of benzene. (b) Compression of an ideal gas at constant temperature. (c) Reaction of sodium with water. (d) Boiling liquid ammonia. (e) Heating a gas at constant volume. (f) Melting of ice.
For which of the following reactions does \(\Delta H_{\mathrm{rxn}}^{\circ}=\) \(\Delta H_{\mathrm{f}}^{\circ} ?\) (a) \(\mathrm{H}_{2}(\mathrm{~g})+\mathrm{S}\) (rhombic) \(\longrightarrow \mathrm{H}_{2} \mathrm{~S}(\mathrm{~g})\) (b) \(\mathrm{C}(\) diamond \()+\mathrm{O}_{2}(g) \longrightarrow \mathrm{CO}_{2}(g)\) (c) \(\mathrm{H}_{2}(g)+\mathrm{CuO}(s) \longrightarrow \mathrm{H}_{2} \mathrm{O}(l)+\mathrm{Cu}(s)\) (d) \(\mathrm{O}(g)+\mathrm{O}_{2}(g) \longrightarrow \mathrm{O}_{3}(g)\)
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