Chapter 9: Problem 28
What is the difference between a Lewis dot symbol and a Lewis structure?
Chapter 9: Problem 28
What is the difference between a Lewis dot symbol and a Lewis structure?
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Get started for freeFor each of the following pairs of elements, state whether the binary compound they form is likely to be ionic or covalent. Write the empirical formula and name of the compound: (a) I and \(\mathrm{Cl}\), (b) \(\mathrm{Mg}\) and \(\mathrm{F}\).
(a) From these data: $$ \begin{aligned} \mathrm{F}_{2}(g) \longrightarrow 2 \mathrm{~F}(g) & \Delta H_{\mathrm{rxn}}^{\circ}=156.9 \mathrm{~kJ} / \mathrm{mol} \\ \mathrm{F}^{-}(g) \longrightarrow \mathrm{F}(g)+e^{-} & \Delta H_{\mathrm{rxn}}^{\circ}=333 \mathrm{~kJ} / \mathrm{mol} \\ \mathrm{F}_{2}^{-}(g) \longrightarrow \mathrm{F}_{2}(g)+e^{-} & \Delta H_{\mathrm{rxn}}^{\circ}=290 \mathrm{~kJ} / \mathrm{mol} \end{aligned} $$ calculate the bond enthalpy of the \(\mathrm{F}_{2}^{-}\) ion. (b) Explain the difference between the bond enthalpies of \(\mathrm{F}_{2}\) and \(\mathrm{F}_{2}^{-}\).
Draw Lewis structures of these organic molecules: (a) methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right) ;\) (b) ethanol \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\right)\); (c) tetraethyllead \(\left[\mathrm{Pb}\left(\mathrm{CH}_{2} \mathrm{CH}_{3}\right)_{4}\right]\), which was used in "leaded" gasoline; (d) methylamine \(\left(\mathrm{CH}_{3} \mathrm{NH}_{2}\right)\) (e) mustard gas \(\left(\mathrm{ClCH}_{2} \mathrm{CH}_{2} \mathrm{SCH}_{2} \mathrm{CH}_{2} \mathrm{Cl}\right)\), a poison- ous gas used in World War I; (f) urea \(\left[\left(\mathrm{NH}_{2}\right)_{2} \mathrm{CO}\right]\), a fertilizer; (g) glycine \(\left(\mathrm{NH}_{2} \mathrm{CH}_{2} \mathrm{COOH}\right)\), an amino acid.
Write Lewis dot symbols for the following ions: (a) \(\mathrm{Li}^{+},(\mathrm{b}) \mathrm{Cl}^{-},(\mathrm{c}) \mathrm{S}^{2-},(\mathrm{d}) \mathrm{Sr}^{2+}\) (e) \(\mathrm{N}^{3+}\).
Write Lewis structures for \(\mathrm{SeF}_{4}\) and \(\mathrm{SeF}_{6}\). Is the octet rule satisfied for Se?
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