Chapter 9: Problem 39
Summarize the essential features of the Lewis octet rule. The octet rule applies mainly to the second period elements. Explain.
Chapter 9: Problem 39
Summarize the essential features of the Lewis octet rule. The octet rule applies mainly to the second period elements. Explain.
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Get started for freeFrom these data, calculate the average bond enthalpy for the \(\mathrm{N}-\mathrm{H}\) bond: $$ \begin{array}{cl} \mathrm{NH}_{3}(g) \longrightarrow \mathrm{NH}_{2}(g)+\mathrm{H}(g) & \Delta H^{\circ}=435 \mathrm{~kJ} / \mathrm{mol} \\ \mathrm{NH}_{2}(g) \longrightarrow \mathrm{NH}(g)+\mathrm{H}(g) & \Delta H^{\circ}=381 \mathrm{~kJ} / \mathrm{mol} \\ \mathrm{NH}(g) \longrightarrow \mathrm{N}(g)+\mathrm{H}(g) & \Delta H^{\circ}=360 \mathrm{~kJ} / \mathrm{mol} \end{array} $$
Write Lewis structures for \(\mathrm{SeF}_{4}\) and \(\mathrm{SeF}_{6}\). Is the octet rule satisfied for Se?
Use Lewis dot symbols to show the transfer of electrons between the following atoms to form cations and anions: (a) \(\mathrm{Na}\) and \(\mathrm{F},\) (b) \(\mathrm{K}\) and \(\mathrm{S},\) (c) \(\mathrm{Ba}\) and \(\mathrm{O}\), (d) \(\mathrm{Al}\) and \(\mathrm{N}\).
Why does the octet rule not hold for many compounds containing elements in the third period of the periodic table and beyond?
Match each of these energy changes with one of the processes given: ionization energy, electron affinity, bond enthalpy, standard enthalpy of formation. (a) \(\mathrm{F}(g)+e^{-} \longrightarrow \mathrm{F}^{-}(g)\) (b) \(\mathrm{F}_{2}(g) \longrightarrow 2 \mathrm{~F}(g)\) (c) \(\mathrm{Na}(g) \longrightarrow \mathrm{Na}^{+}(g)+e^{-}\) (d) \(\mathrm{Na}(s)+\frac{1}{2} \mathrm{~F}_{2}(g) \longrightarrow \mathrm{NaF}(s)\)
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