Chapter 9: Problem 64
Write Lewis structures for the reaction $$ \mathrm{AlCl}_{3}+\mathrm{Cl}^{-} \longrightarrow \mathrm{AlCl}_{4}^{-} $$ What kind of bond is between \(\mathrm{Al}\) and \(\mathrm{Cl}\) in the product?
Chapter 9: Problem 64
Write Lewis structures for the reaction $$ \mathrm{AlCl}_{3}+\mathrm{Cl}^{-} \longrightarrow \mathrm{AlCl}_{4}^{-} $$ What kind of bond is between \(\mathrm{Al}\) and \(\mathrm{Cl}\) in the product?
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Get started for freeFrom these data, calculate the average bond enthalpy for the \(\mathrm{N}-\mathrm{H}\) bond: $$ \begin{array}{cl} \mathrm{NH}_{3}(g) \longrightarrow \mathrm{NH}_{2}(g)+\mathrm{H}(g) & \Delta H^{\circ}=435 \mathrm{~kJ} / \mathrm{mol} \\ \mathrm{NH}_{2}(g) \longrightarrow \mathrm{NH}(g)+\mathrm{H}(g) & \Delta H^{\circ}=381 \mathrm{~kJ} / \mathrm{mol} \\ \mathrm{NH}(g) \longrightarrow \mathrm{N}(g)+\mathrm{H}(g) & \Delta H^{\circ}=360 \mathrm{~kJ} / \mathrm{mol} \end{array} $$
Without referring to Figure 9.1 , write Lewis dot symbols for atoms of the following elements: (a) Be, (b) \(\mathrm{K},\) (c) \(\mathrm{Ca},\) (d) \(\mathrm{Ga},\) (e) \(\mathrm{O},\) (f) \(\mathrm{Br},(\mathrm{g}) \mathrm{N},(\mathrm{h}) \mathrm{I},\) (i) \(\mathrm{As}\), (j) F.
In the vapor phase, beryllium chloride consists of discrete molecular units \(\mathrm{BeCl}_{2}\). Is the octet rule satisfied for Be in this compound? If not, can you form an octet around Be by drawing another resonance structure? How plausible is this structure?
What is a Lewis dot symbol? To what elements does the symbol mainly apply?
Specify which compound in the following pairs of ionic compounds has the higher lattice energy: (a) \(\mathrm{KCl}\) or \(\mathrm{MgO},\) (b) \(\mathrm{LiF}\) or \(\mathrm{LiBr}\) (c) \(\mathrm{Mg}_{3} \mathrm{~N}_{2}\) or \(\mathrm{NaCl}\). Explain your choice.
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