Which of the following ions has the electron configuration of a noble gas: \(\mathrm{Ca}^{+}\) or \(\mathrm{Cl}^{-} ?\) (Hint: Write the electron configuration for each ion.)

Short Answer

Expert verified
The ion with a noble gas electron configuration is \(\mathrm{Cl}^{-}\).

Step by step solution

01

First Step: Understand Noble Gas Electron Configuration

In the periodic table, noble gases are in the Group 18. They are known for their stability because they have full electron shells or energy levels. This means that they have achieved the octet rule, having eight electrons in their outermost shell (except helium which has two). This stability is what other atoms seek to achieve through gaining, losing, or sharing electrons.
02

Second Step: Write the Electron Configurations for Ca+ and Cl-

Calcium (\(\mathrm{Ca}\)) has 20 electrons in its neutral state, but as \(\mathrm{Ca}^{+}\), it loses one electron, leaving it with 19 electrons. Chlorine (\(\mathrm{Cl}\)) has 17 electrons in its neutral state, but as \(\mathrm{Cl}^{-}\), it gains one electron, giving it 18 electrons.
03

Third Step: Match to a Noble Gas

On comparing these configurations with that of noble gases, \(\mathrm{Cl}^{-}\) with 18 electrons matches the electron configuration of Argon (Ar), a noble gas. However, \(\mathrm{Ca}^{+}\) with 19 electrons does not match any noble gas configuration.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Electron Configuration
Electron configuration is a fundamental concept in chemistry that describes the distribution of electrons in an atom's atomic orbitals. Understanding electron configuration is crucial for predicting an element’s chemical behavior.

Electrons occupy regions around the nucleus known as orbitals, and they fill these orbitals in a specific order based on their energy levels. The lowest energy orbitals get filled first, which is often summarized by the aufbau principle. Hund's rule and the Pauli exclusion principle are additional rules that guide electron configuration.

An atom seeks the most stable configuration possible. The stability can often be linked to how the valence electrons are distributed, and whether they match the electron configuration of noble gases, which are the epitome of electron configuration stability due to their full valence shells.
Octet Rule
The octet rule is a chemical principle that reflects the observation that atoms of main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas. The rule is applicable to the elements of the s- and p-block elements of the periodic table.

This rule is based on the pattern that noble gases (except helium) naturally contain eight electrons in their outermost shell, making them exceptionally stable. Atoms with fewer or more than eight electrons will usually attempt to donate, accept, or share electrons through bonds to achieve a stable octet arrangement. Understanding the octet rule is crucial for predicting the bonding behavior of an element and the formation of molecules or compounds.
Periodic Table
The periodic table is a tabular display of the chemical elements, arranged by atomic number, electron configuration, and recurring chemical properties. Elements are presented in order of increasing atomic number in rows called periods and columns known as groups or families.

The table is divided into blocks corresponding to the characteristic s, p, d, and f subshell electron configurations. The noble gases are located in the rightmost column, known as Group 18. The positioning of elements on the periodic table allows us to predict an element's properties and reactivity.

In educational contexts, the periodic table serves as a powerful tool for students to understand trends such as atomic radii, ionization energies, electronegativities, and the likelihood of an element to gain or lose electrons. Comprehending the periodic table's structure helps students grasp why certain ions have electron configurations that match noble gases and why elements react to follow the octet rule.

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