Write a balanced equation for the combus- tion of octane, \(\mathrm{C}_{8} \mathrm{H}_{18},\) with oxygen to obtain carbon dioxide and water. What is the mole ratio of oxygen to octane?

Short Answer

Expert verified
The balanced equation is \(2C_8H_{18} + 25O_2 \rightarrow 16CO_2 + 18H_2O\). The mole ratio of oxygen to octane is 25:2.

Step by step solution

01

Identify the Unbalanced Chemical Reaction

The combustion of octane, \(C_8H_{18}\), in oxygen produces carbon dioxide and water. The unbalanced chemical reaction can be written as: \(C_8H_{18} + O_2 \rightarrow CO_2 + H_2O\)
02

Balance the Chemical Reaction

On the right side of the equation, there are 16 hydrogen atoms and 8 carbon atoms. Therefore, to balance the equation, 8 molecules of carbon dioxide and 9 molecules of water are needed: \( C_8H_{18} + O_2 \rightarrow 8CO_2 + 9H_2O \) Lastly, balance the oxygen atoms. There are 25 oxygen atoms on the right side, so 12.5 oxygen molecules are needed on the left side. However, the equation must have whole numbers, so you double all coefficients to get rid of the fractional coefficient: \( 2C_8H_{18} + 25O_2 \rightarrow 16CO_2 + 18H_2O \)
03

Determine the Mole Ratio

The mole ratio is the ratio of coefficients of the two substances in the balanced chemical equation. From the balanced equation, it can be seen that the mole ratio of oxygen to octane is 25:2.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Chemical Reactions
A chemical reaction is a process where substances, referred to as reactants, transform into different substances, known as products. This transformation occurs through the breaking and forming of chemical bonds. An essential aspect of a chemical reaction is that it must adhere to the law of conservation of mass, which dictates that the total mass of the reactants must equal the total mass of the products.

Understanding this concept is crucial when studying the combustion of octane, where octane and oxygen are the reactants that react to form carbon dioxide and water, the products. The process releases energy, which is characteristic of combustion reactions. To use this theory, we must write down the initial, unbalanced reaction and then systematically adjust the coefficients of each reactant and product until the equation is balanced, ensuring no atoms are lost in the process.
The Role of Stoichiometry in Chemical Equations
Stoichiometry is a branch of chemistry that deals with the quantitative relationships between the reactants and products in a chemical reaction. It involves calculations that relate the amounts of substances involved in a reaction.

In the context of balancing the equation for the combustion of octane, stoichiometry is used to find the right coefficients that will balance the equation. It requires a meticulous process of balancing each element on both sides of the chemical equation. For instance, the oxygen molecules in the reactants must be equal in number to the oxygen atoms in the carbon dioxide and water molecules in the products. By using stoichiometry, we can also calculate the amounts of substances needed for a reaction or produced by a reaction in terms of moles, mass, or volume.
Deciphering Mole Ratios in Balanced Equations
The mole ratio is an expression of the relative amounts of moles of reactants and products in a balanced chemical equation. It is derived from the coefficients in a balanced equation, which indicate the proportions of each substance involved in the reaction.

For the combustion of octane, the balanced equation shows that for every 2 moles of octane (C8H18), 25 moles of oxygen (O2) are required. Thus, the mole ratio of oxygen to octane is 25:2. This mole ratio is essential for scientists and engineers, for instance, when designing engines, as it ensures the correct amounts of reactants for efficient combustion, avoiding excess or deficiency of any reactant. As an important stoichiometric concept, the mole ratio is a critical factor determining the quantitative outcome of chemical processes.

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Most popular questions from this chapter

Use the equation provided to answer the questions that follow. $$2 \mathrm{NO}+\mathrm{O}_{2} \longrightarrow 2 \mathrm{NO}_{2}$$ \begin{equation}\begin{array}{l}{\text { a. How many molecules of } \mathrm{NO}_{2} \text { can form }} \\ {\text { from } 1.11 \mathrm{mol} \mathrm{O}_{2} \text { and excess } \mathrm{NO} \text { ? }} \\ {\text { b. How many molecules of NO will react }} \\ {\text { with } 25.7 \mathrm{g} \mathrm{O}_{2} ?} \\ {\text { c. How many molecules of } \mathrm{O}_{2} \text { are needed to }} \\ {\text { make } 3.76 \times 10^{22} \text { molecules } \mathrm{NO}_{2} ?}\end{array}\end{equation}

The percentage yield of nitric acid is 95\(\% .\) If 9.88 \(\mathrm{kg}\) of nitrogen dioxide react, what mass of nitric acid is isolated? $$3 \mathrm{NO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g) \rightarrow 2 \mathrm{HNO}_{3}(a q)+\mathrm{NO}(g)$$

In the reaction shown below, 64 \(\mathrm{g} \mathrm{CaC}_{2}\) is reacted with 64 \(\mathrm{g} \mathrm{H}_{2} \mathrm{O} .\) $$\mathrm{CaC}_{2}(s)+2 \mathrm{H}_{2} \mathrm{O}(l) \rightarrow \mathrm{C}_{2} \mathrm{H}_{2}(g)+\mathrm{Ca}(\mathrm{OH})_{2}(s)$$ \begin{equation}\begin{array}{l}{\text { a. Which is the excess reactant, and which is }} \\ {\text { the limiting reactant? }} \\ {\text { b. What is the theoretical yield of } C_{2} \mathrm{H}_{2} ?} \\ {\text { c. What is the theoretical yield of } \mathrm{Ca}(\mathrm{OH})_{2} ?}\end{array}\end{equation}

Why would it be unreasonable for an amendment to the Clean Air Act to call for 0% pollution emissions from cars with combustion engines?

Nitrogen monoxide, NO, reacts with oxygen to form nitrogen dioxide. Then the nitrogen dioxide reacts with oxygen to form nitrogen monoxide and ozone. Write the balanced equations. What is the theoretical yield in grams of ozone from 4.55 g of nitrogen monoxide with excess \(\mathrm{O}_{2} ?\) (Hint: First calcu- late the theoretical yield for NO \(_{2}\) , then use that value to calculate the yield for ozone.)

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