The following reaction can be used to remove \(\mathrm{CO}_{2}\) breathed out by astronauts in a spacecraft. $$2 \mathrm{LiOH}(s)+\mathrm{CO}_{2}(g) \rightarrow \mathrm{Li}_{2} \mathrm{CO}_{3}(s)+\mathrm{H}_{2} \mathrm{O}(l)$$ \begin{equation}\begin{array}{l}{\text { a. How many grams of carbon dioxide can }} \\ {\text { be removed by } 5.5 \text { mol LiOH? }} \\ {\text { b. How many milliliters } \mathrm{H}_{2} \mathrm{O} \text { (density }=} \\\ {0.997 \mathrm{g} / \mathrm{mL} \text { ) could form from } 25.7 \mathrm{g} \text { LiOH? }} \\ {\text { c. How many molecules } \mathrm{H}_{2} \mathrm{O} \text { could be }} \\ {\text { made when } 3.28 \mathrm{g} \mathrm{CO}_{2} \text { react? }}\end{array}\end{equation}

Short Answer

Expert verified
a. About 122.8 g of CO2 can be removed by 5.5 mol of LiOH. b. 865.5 mL of water could form from 25.7 g of LiOH. c. Around \(4.95 \times 10^{23}\) molecules of water could be made when 3.28 g of \(CO_{2}\) reacts.

Step by step solution

01

Identify and Convert

Firstly, identify the balanced equation given: \(2 \mathrm{LiOH}(s)+\mathrm{CO}_{2}(g) \rightarrow \mathrm{Li}_{2} \mathrm{CO}_{3}(s)+\mathrm{H}_{2} \mathrm{O}(l).\n For part a: Given that 5.5 mol of LiOH reacts, determine the moles of \(\mathrm{CO}_{2}\) using the balanced equation: \(5.5 mol \ LiOH \times \frac{1 mol \ CO_{2}}{2 mol \ LiOH}\).
02

Molar Mass Calculation

Next, calculate the molar mass of \(CO_{2}\) to convert moles of \(CO_{2}\) to grams: \(1 mol \ CO_{2} = 44.01 g \ CO_{2}\). Hence, multiply the result of step 1 with the molar mass of \(CO_{2}\) to find how many grams can be removed.
03

Volume of water formation

For part b: Given that 25.7 g of LiOH react, convert this to moles using its molar mass (23.95 g/mol). Subsequently, using the balanced equation, convert moles of LiOH to moles of \(H_{2}O\). Then convert moles of \(H_{2}O\) to grams using its molar mass (18.02 g/mol). Lastly, convert grams of \(H_{2}O\) to milliliters using the given density.
04

Quantity of water molecules

For part c: Start by converting the given mass of \(CO_{2}\) to moles using its molar mass. Using the balanced equation, convert moles of \(CO_{2}\) to moles of \(H_{2}O\). To determine the number of molecules, use Avogadro's number (\(6.022 \times 10^{23} molecules/mol\)).

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Most popular questions from this chapter

Graphing Calculator Calculating Percentage Yield of a Chemical Reaction The graphing calculator can run a program that calculates the percentage yield of a chemical reaction when you enter the actual yield and the theoretical yield. Using an example in which the actual yield is 38.8 g and the theoretical yield is 53.2 g, you will calculate the percentage yield. First, the pro- gram will carry out the calculation. Then you can use it to make other calculations. Go to Appendix C. If you are using a TI-83 Plus, you can download the program YIELD and data and run the application as directed. If you are using another calculator, your teacher will provide you with keystrokes and data sets to use. After you have run the program, answer the questions. Note: all answers are written with three significant figures. \begin{equation}\begin{array}{l}{\text { a. What is the percentage yield when the }} \\ {\text { actual yield is } 27.3 \mathrm{g} \text { and the theoretical }} \\ {\text { yield is } 44.6 \mathrm{g} \text { ? }} \\ {\text { b. What is the percentage yield when the }} \\ {\text { actual yield is } 5.40 \mathrm{g} \text { and the theoretical }} \\ {\text { c. What actual yield theoretical yield pair }} \\ {\text { produced the largest percentage yield? }}\end{array}\end{equation}

Use the equation provided to answer the questions that follow. $$2 \mathrm{Na}+2 \mathrm{H}_{2} \mathrm{O} \longrightarrow 2 \mathrm{NaOH}+\mathrm{H}_{2}$$ \begin{equation}\begin{array}{l}{\text { a. How many molecules of } \mathrm{H}_{2} \text { could be }} \\ {\text { made from } 27.6 \mathrm{g} \mathrm{H}_{2} \mathrm{O} \text { ? }} \\ {\text { b. How many atoms of Na will completely }} \\ {\text { react with } 12.9 \mathrm{g} \mathrm{H}_{2} \mathrm{O} \text { ? }} \\ {\text { c. How many molecules of } \mathrm{H}_{2} \text { could form }} \\ {\text { when } 6.59 \times 10^{20} \text { atoms Na react? }}\end{array}\end{equation}

What is the key conversion factor needed to solve all stoichiometry problems?

Oxygen can be prepared by heating potassium chlorate. $$2 \mathrm{KClO}_{3}(s) \rightarrow 2 \mathrm{KCl}(s)+3 \mathrm{O}_{2}(g)$$ \begin{equation}\begin{array}{l}{\text { a. What mass of } \mathrm{O}_{2} \text { can be made from heat- }} \\ {\text { ing } 125 \text { g of } \mathrm{KClO}_{3} ?} \\ {\text { b. How many grams of } \mathrm{KClO}_{3} \text { are needed }} \\ {\text { to make } 293 \mathrm{g} \mathrm{g}_{2} \text { ? }} \\ {\text { c. How many grams of KCl could form from }} \\\ {20.8 \mathrm{g} \mathrm{KClO}_{3} ?}\end{array}\end{equation}

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