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Chapter 22: Problem 10

What are cycloalkanes?

Short Answer

Expert verified
Cycloalkanes are hydrocarbons with carbon atoms arranged in a ring, having a general formula of \( C_nH_{2n} \).

Step by step solution

01

Understand the Definition

Cycloalkanes are a type of hydrocarbon. Just like alkanes, they consist only of hydrogen and carbon atoms, but they differ in their structure.
02

Recognize the Structural Difference

Unlike linear or branched alkanes, cycloalkanes form a ring structure. This means the carbon atoms are connected in such a way that they create a closed loop.
03

Identify the Formula

The general formula for cycloalkanes is \( C_nH_{2n} \). This means that for every 'n' number of carbon atoms, there are '2n' hydrogen atoms.
04

Examples

An example of a cycloalkane is cyclohexane with the formula \( C_6H_{12} \). It consists of a six-carbon ring, each bonded to two hydrogen atoms.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Hydrocarbons
Hydrocarbons are organic compounds made up of only hydrogen and carbon atoms. They are the simplest form of organic molecules and can be either aliphatic (straight or branched chains) or cyclic (ring structures). Cycloalkanes belong to the cyclic category of hydrocarbons. These compounds are important because they are the basic building blocks of many complex organic molecules.

Hydrocarbons are usually divided into different groups based on their structure and the type of bonds between the carbon atoms. The main categories are:
  • Alkanes - single bonds (saturated)
  • Alkenes - double bonds (unsaturated)
  • Alkynes - triple bonds (unsaturated)
  • Cycloalkanes - ring structures (saturated)
These categories help chemists understand and predict the properties and reactions of these compounds.
Ring Structure
Cycloalkanes are characterized by their ring structure. Unlike linear or branched alkanes, cycloalkanes form closed loops, where the carbon atoms are connected in such a way that they create a continuous ring. This ring formation influences the physical and chemical properties of cycloalkanes.

The simplest cycloalkane is cyclopropane, which has a three-carbon ring. As the number of carbon atoms increases, the rings become larger. For example:
  • Cyclobutane - four carbon atoms
  • Cyclopentane - five carbon atoms
  • Cyclohexane - six carbon atoms
The ring structure adds a certain degree of rigidity and stability to the molecule, which affects how it behaves in various chemical reactions.
General Formula
The general formula for cycloalkanes is \( C_nH_{2n} \). This formula indicates that for every 'n' number of carbon atoms, there are '2n' hydrogen atoms. The general formula helps to identify and distinguish cycloalkanes from other hydrocarbons. For example:

  • For n=3 (cyclopropane), the formula is \( C_3H_6 \)
  • For n=4 (cyclobutane), the formula is \( C_4H_8 \)
  • For n=5 (cyclopentane), the formula is \( C_5H_{10} \)
Knowing the general formula enables chemists to predict the number of hydrogen atoms in a cycloalkane based on the number of carbon atoms. This is different from the general formula for linear alkanes, which is \( C_nH_{2n+2} \). Understanding this distinction is crucial for students studying hydrocarbon chemistry.

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Most popular questions from this chapter

Inferring Conclusions Why are organic compounds with covalent bonds usually less stable when heated than inorganic compounds with ionic bonds?

Can molecules with the molecular formulas \(\mathrm{C}_{4} \mathrm{H}_{10}\) and \(\mathrm{C}_{4} \mathrm{H}_{10} \mathrm{O}\) be structural isomers of one another? Why or why not?

Based on the boiling points of water and methanol, in which would you expect to observe a greater degree of hydrogen bonding? Explain your answer.

Consult reference materials at the library, and read about products made from hydrocarbons. Keep a list of the number of petroleum-related products you use in a single day.

a. What are delocalized electrons? b. What is their effect on the reactivity of aromatic hydrocarbons?
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