Chapter 1: Problem 10
Optically active 2 -iodobutane on treatment with NaI, loses its optical activity. Explain why.
Chapter 1: Problem 10
Optically active 2 -iodobutane on treatment with NaI, loses its optical activity. Explain why.
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Get started for freeA meso compound (a) is an achiral molecule, which contain chiral carbons. (b) contains a plane of symmetry or a centre of symmetry. (c) is optically inactive due to internal compensation. (d) is characterized by all the above.
A chemical reaction is one in which old bonds are broken and new bonds are made. During the course of these changes a variety of intermediates are formed before a starting material is converted to final products. Formation of these intermediates depend on several factors like bond energies, kinetics of the reactions etc. Identify the correct statement among the following. (a) An electrophile has always a positive charge. (b) \(\mathrm{CN}^{-}\) can act as an ambident nucleophile. (c) The carbon species A formed is a methyl carbanion. (d) In \(\mathrm{CH}_{3} \mathrm{MgBr}\), the methyl group carries slight positive charge.
(+) Mandelic acid has an optical rotation of \(+158^{\circ}\). What would be the specific rotation of a mixture of \(25 \%(-)\) and \(75 \%\) (+) mandelic acid? (a) \(+118.5^{\circ}\) (b) \(-118.5^{\circ}\) (c) \(-79^{\circ}\) (d) \(+79^{\circ}\)
IUPAC name of the compound (a) Trans-3,4-dimethylhex-3-ene (b) Cis- 3,4 -dimethylhex-3-ene (c) Cis- 3,4 -dimethylhex-4-ene (d) Cis-2,3-diethylbut-2-ene
The correct decreasing order of acidity is (a) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{OH}>\mathrm{HC}=\mathrm{CH}>\mathrm{H}_{2} \mathrm{O}>\mathrm{NH}_{3}\) (b) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{OH}>\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}>\mathrm{NH}_{3}>\mathrm{HC}=\mathrm{CH}\) (c) \(\mathrm{HC}=\mathrm{CH}>\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{OH}>\mathrm{H}_{2} \mathrm{O}>\mathrm{NH}_{3}\) (d) \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{OH}>\mathrm{H}_{2} \mathrm{O}>\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}>\mathrm{HC}=\mathrm{CH}\)
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