Chapter 2: Problem 134
(a) 4 -chloro- 1 -methylcyclohexane (b) trans 4 -chloro- 1 -methylcyclohexane (c) trans 1 -chloro-4-methylcyclohexane (d) trans 1 -methyl-4-chlorocyclohexane
Chapter 2: Problem 134
(a) 4 -chloro- 1 -methylcyclohexane (b) trans 4 -chloro- 1 -methylcyclohexane (c) trans 1 -chloro-4-methylcyclohexane (d) trans 1 -methyl-4-chlorocyclohexane
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Get started for free\(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{3} \stackrel{\mathrm{Br}_{2} / \mathrm{hv}}{\longrightarrow}(\mathrm{A}) \stackrel{\mathrm{Mg} / \mathrm{Ether}}{\longrightarrow}(\mathrm{B}) \stackrel{\mathrm{D}_{2} \mathrm{O}}{\longrightarrow}(\mathrm{C})\) The major product \(C\) formed is (a) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{D}\) (b) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{3}\) (c) \(\mathrm{CH}_{3} \mathrm{CHD} \mathrm{CH}_{3}\) (d)
(A) and (B) are respectively (a) But-2-yne and but-2-ene (b) But-2-ene and but-2-yne (c) Butane and but-2-ene (d) But-2-ene and butane
Directions: Each question contains Statement-1 and Statement-2 and has the following choices (a), (b), (c) and (d), out of which ONLY ONE is correct. (a) Statement- 1 is True, Statement- 2 is True; Statement- 2 is a correct explanation for Statement-1 (b) Statement- 1 is True, Statement- 2 is True; Statement- 2 is NOT a correct explanation for Statement-1 (c) Statement-1 is True, Statement- 2 is False (d) Statement- 1 is False, Statement- 2 is True Statement 1 Oxymercuration reduction of an alkene gives an alcohol in which the -OH group is added to a more branched carbon of the double bond, while hydroboration- oxidation of an alkene gives an alcohol in which the -OH group is added to a less branched carbon of the alkene. and Statement 2 Hydration of an alkene in the presence of an acid is one of the standard methods of preparation of an alcohol form alkenes.
Each question in this section has four suggested answers out of which ONE OR MORE answers will be correct. Which of the following statements is correct? (a) Cyclopropane will react with chlorine or bromine at room temperature, in diffused light to give a dihalogen derivative. (b) A hydrocarbon of molecular formula \(\mathrm{C}_{4} \mathrm{H}_{6}\) should contain always a triple bond. (c) The trans isomer of an alkene is generally less polar than the cis isomer. (d) \(\mathrm{H}_{2} \mathrm{C}=\mathrm{CH}-\mathrm{CH}_{2}-\mathrm{CH}=\mathrm{CH}_{2}\) is an example of cumulated diene.
Which group or atom in each of the following pairs gets priority according to CIP rules used for assigning \(\mathrm{R}\) and \(\mathrm{S}\) configuration for chiral molecules? (a) \(-\mathrm{CH}_{2} \mathrm{OH}\) or \(-\mathrm{CH}_{2} \mathrm{Cl}\) (b) \(-\mathrm{CH}=\mathrm{CH}_{2}\) or \(-\mathrm{CH}_{2} \mathrm{CH}_{3}(\mathrm{c})-\mathrm{NH}_{2}\) or \(-\mathrm{OH}\) (d) \(-\mathrm{CH}_{2} \mathrm{OH}\) or \(-\mathrm{CHO}\) Choose from the options given below \(\begin{array}{llll}\text { (a) } \mathrm{A}:-\mathrm{CH}_{2} \mathrm{OH}, & \mathrm{B}:-\mathrm{CH}=\mathrm{CH}_{2}, & \mathrm{C}:-\mathrm{NH}_{2}, & \mathrm{D}:-\mathrm{CHO}\end{array}\) \(\begin{array}{llll}\text { (b) } \mathrm{A}:-\mathrm{CH}_{2} \mathrm{Cl}, & \mathrm{B}:-\mathrm{CH}=\mathrm{CH}_{2}, & \mathrm{C}:-\mathrm{OH}, & \mathrm{D}:-\mathrm{CHO}\end{array}\) \(\begin{array}{llll}\text { (c) } \mathrm{A}:-\mathrm{CH}_{2} \mathrm{OH}, & \mathrm{B}:-\mathrm{CH}_{2} \mathrm{CH}_{3}, & \mathrm{C}:-\mathrm{NH}_{2}, & \mathrm{D}:-\mathrm{CHO}\end{array}\) \(\begin{array}{llll}\text { (d) } \mathrm{A}:-\mathrm{CH}_{2} \mathrm{Cl}, & \mathrm{B}:-\mathrm{CH}_{2}-\mathrm{CH}_{3}, & \mathrm{C}:-\mathrm{OH}, & \mathrm{D}:-\mathrm{CH}_{2} \mathrm{OH}\end{array}\)
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