A hydrocarbon having only primary hydrogens is (a) Cyclohexane (b) 2-methylpropane (c) 2, 3 dimethyl but-2-ene (d) \(\mathrm{n}\) - butane

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a) Cyclohexane b) 2-methylpropane c) 2, 3 dimethyl but-2-ene d) \(\mathrm{n}\) - butane Answer: b) 2-methylpropane

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01

Choice (a): Cyclohexane

Cyclohexane is a ring structure containing six carbon atoms attached to form a hexagon. Each carbon atom is bonded to two hydrogen atoms. However, each carbon atom is also bonded to two other carbon atoms (in a ring), which makes it a secondary carbon, and therefore, its hydrogens are not primary.
02

Choice (b): 2-methylpropane

2-methylpropane has the following structure: \(\mathrm{CH_3-CH(CH_3)_2}\). Here, the central carbon atom is called a tertiary carbon because it is bonded to three other carbon atoms. The other three carbon atoms are primary carbons because they are bonded to only one other carbon atom. So, 2-methylpropane has only primary hydrogens attached to its primary carbons, making it a possible answer.
03

Choice (c): 2, 3 dimethyl but-2-ene

2, 3 dimethyl but-2-ene has the following structure: \(\mathrm{CH_3-C(CH_3)=CH-C(CH_3)_2}\). In this compound, the carbon atom with the double bond (C=C) is called a quaternary carbon. It is bonded to three other carbons, making it a tertiary carbon, while the other three carbons are bonded to only one other carbon atom (primary carbons). The hydrogens on the primary carbons are primary hydrogens, but the quaternary carbon has no hydrogens attached, indicating that this compound doesn't have only primary hydrogens.
04

Choice (d): \(\mathrm{n}\) - butane

\(\mathrm{n}\) -butane has the following structure: \(\mathrm{CH_3-CH_2-CH_2-CH_3}\). The carbon atoms at the ends (first and fourth positions) are attached to only one other carbon atom, making them primary carbons, while the other two carbon atoms in the middle are attached to two other carbon atoms making them secondary carbons. The two primary carbons have three primary hydrogens attached to them while the two secondary carbons have two secondary hydrogens attached to them. Thus, this compound doesn't have only primary hydrogens. Based on all provided choices, the only compound that has only primary hydrogens is: 2-methylpropane (choice b).

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