Match the elements of Column I to elements of Column II. There can be single or multiple matches. Column I (a) Neopentane (b) Cyclohexane (c) 2,2 -dimethyl butane (d) \(2,2,3,3-\) tetramethyl butane Column II (p) equatorial hydrogens (q) Secondary hydrogens (r) Quaternary carbon (s) Only one monochloro derivative

Short Answer

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Question: Match the compounds in Column I with the features in Column II: Column I (a) Neopentane (b) Cyclohexane (c) 2,2-dimethyl butane (d) 2,2,3,3-tetramethyl butane Column II (p) equatorial hydrogens (q) Secondary hydrogens (r) Quaternary carbon (s) Only one monochloro derivative Answer: (a) Neopentane - (r) Quaternary carbon & (s) Only one monochloro derivative (b) Cyclohexane - (p) equatorial hydrogens & (q) Secondary hydrogens (c) 2,2-dimethyl butane - (q) Secondary hydrogens (d) 2,2,3,3-tetramethyl butane - (r) Quaternary carbon

Step by step solution

01

Identify the compounds

Draw the structural formulas of the compounds in Column I as follows: (a) Neopentane (b) Cyclohexane (c) 2,2-dimethyl butane (d) 2,2,3,3-tetramethyl butane
02

Identify the features

Look for the features mentioned in Column II: (p) equatorial hydrogens (q) Secondary hydrogens (r) Quaternary carbon (s) Only one monochloro derivative
03

Analyze the matches

Now, let's proceed to match the elements from both the columns. (a) Neopentane Neopentane has a quaternary carbon and it forms only one monochloro derivative. Thus, it matches with (r) and (s). (b) Cyclohexane Cyclohexane has equatorial hydrogens in its chair conformation as well as secondary hydrogens. Thus, it matches with (p) and (q). (c) 2,2-dimethyl butane 2,2-dimethyl butane also has secondary hydrogens. Thus, it matches (q). (d) \(2,2,3,3-\) tetramethyl butane 2,2,3,3-tetramethyl butane has quaternary carbon. Thus, it matches (r). So, the matches are as follows: Column I - Column II (a) Neopentane - (r) Quaternary carbon & (s) Only one monochloro derivative (b) Cyclohexane - (p) equatorial hydrogens & (q) Secondary hydrogens (c) 2,2-dimethyl butane - (q) Secondary hydrogens (d) \(2,2,3,3-\) tetramethyl butane - (r) Quaternary carbon

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Most popular questions from this chapter

The total number of chlorinated products given by ethane is (a) 6 (b) 7 (c) 8 (d) 9

The product formed when ethene and air under pressure is passed over silver catalyst heated to \(500 \mathrm{~K}\) is (a) Epoxy ethane (b) Ethanal (c) Ethanoic acid (d) Methanal

Directions: Each question contains Statement-1 and Statement-2 and has the following choices (a), (b), (c) and (d), out of which ONLY ONE is correct. (a) Statement- 1 is True, Statement- 2 is True; Statement- 2 is a correct explanation for Statement-1 (b) Statement- 1 is True, Statement- 2 is True; Statement- 2 is NOT a correct explanation for Statement-1 (c) Statement-1 is True, Statement- 2 is False (d) Statement- 1 is False, Statement- 2 is True Statement 1 Boiling point of n-pentane is higher than that of neopentane while the melting point of \(n\) -pentane is lower than that of neopentane. and Statement 2 Boiling point of alkanes depend upon the surface area while melting point depends upon the packing of molecules in the solid state. Neopentane fits into the crystal lattice more readily and it has minimum surface area compared to n-pentane.

The number of structural and stereoisomers of a bromo compound \(\mathrm{C}_{5} \mathrm{H}_{9} \mathrm{Br}\) formed by the addition of \(\mathrm{HBr}\) to pent- 2 yne are respectively (a) 4 and 2 (b) 1 and 2 (c) 2 and 4 (d) 2 and 1

Which of the following statements is correct? (a) Ethylene show conformational isomerism. (b) Hex-3-ene does not show peroxide effect on treatment with HBr in presence of peroxides. (c) When but-1-ene is treated with excess of bromine, the product obtained is 2 -bromobutane. (d) Reactivity order of the hydrocarbons is alkane < alkenes < alkynes.

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