Chapter 2: Problem 96
An alkene on reductive as well as oxidative ozonolysis gave only one product. The alkene is (a) propene (b) 2,3-dimethyl-2-butene (c) pent-2-ene (d) 2 -methyl propene
Chapter 2: Problem 96
An alkene on reductive as well as oxidative ozonolysis gave only one product. The alkene is (a) propene (b) 2,3-dimethyl-2-butene (c) pent-2-ene (d) 2 -methyl propene
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Get started for free\(\mathrm{H}_{3} \mathrm{C}-\mathrm{C} \equiv \mathrm{CH}+\mathrm{CH}_{3} \mathrm{MgI} \longrightarrow(\mathrm{A})+\mathrm{CH}_{4}\) \((\mathrm{A})+\mathrm{CH}_{3} \mathrm{I} \longrightarrow(\mathrm{B})+\mathrm{MgI}_{2}\) (A) and (B) are (a) \(\mathrm{H}-\mathrm{C} \equiv \mathrm{C}-\mathrm{MgI}\) and \(\mathrm{CH}_{4}\) (b) \(\mathrm{H}_{3} \mathrm{C}-\mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_{3}\) and \(\mathrm{CH}_{4}\) (c) \(\mathrm{CH}_{3}-\mathrm{C} \equiv \mathrm{C}-\mathrm{MgI}\) and \(\mathrm{CH}_{3}-\mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_{3}\) (d) \(\mathrm{H}_{3} \mathrm{C}-\mathrm{C} \equiv \mathrm{C}-\mathrm{I}\) and
A hydrocarbon \(\mathrm{C}_{5} \mathrm{H}_{12}\) (A) on treatment with chlorine undergoes monochlorination by the replacement of the only \(1^{\circ}\) hydrogen to give(B) \(\mathrm{C}_{5} \mathrm{H}_{11} \mathrm{Cl}\). When (B) is treated with Na metal in ether, the product obtained could be (a) \(\quad\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH}-\mathrm{CH}\left(\mathrm{CH}_{3}\right)_{2}\) (b) \(\mathrm{CH}_{3}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{2}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{2}-\mathrm{CH}_{3}\) (c) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{3}\) (d) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{C}-\mathrm{CH}_{2} \mathrm{Cl}\)
\(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CuLi}\) is known as (a) Corey-House reagent (b) Gilman reagent (c) Grignard reagent (d) Ullmann reagent
The conversion can be successfully carried out by (a) \(\mathrm{H}^{+} / \mathrm{H}_{2} \mathrm{O}\) (b) Hydroboration-oxidation (c) HBr addition in the presence of peroxides followed by hydrolysis with aqueous KOH (d) Oxymercuration-reduction
Directions: This section contains 1 paragraph. Based upon the paragraph, 3 multiple choice questions have to be answered. Each question has 4 choices (a), (b), (c) and (d), out of which ONLY ONE is correct. Passage I Alkenes undergo a variety of reactions like hydrogenation, halogenation, oxidation, epoxidation and so on. The double bond of the alkenes acts as electron donor. An unsaturated hydrocarbon gave, on treatment with alkaline \(\mathrm{KMnO}_{4}\) under hot conditions, one mole of adipic acid. The unsaturated hydrocarbon could be (a) \(\mathrm{H}_{3} \mathrm{C}-\mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{3}\) (b) \(\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}_{2}-\mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{3}\)
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